Evaluation of laboratory kinetics and photochemical data for atmospheric chemistry applications

被引：19

作者：

Cox, R. A. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Ctr Atmospher Sci, Cambridge CB2 1EW, England

来源：

CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 19期

关键词：

MASTER CHEMICAL MECHANISM; MCM V3 PART; TROPOSPHERIC DEGRADATION; HETEROGENEOUS REACTIONS; N2O5; REACTIVITY; OZONE; TEMPERATURE; PROTOCOL; ACID; HO2+NOREACTION;

D O I：

10.1039/c2cs35092k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This article deals with the evaluation of chemical kinetics and photochemical data for use in atmospheric modeling. Models used to calculate the temporal and spatial variation of atmospheric trace gas composition are based on chemical schemes which require chemical kinetics data for the elementary reactions involved. These data derive from careful experimentation under conditions relevant for the atmosphere, carried out in laboratories worldwide using ever improving technology over the past 50 years. The article contains an account of the background issues of atmospheric composition change which have stimulated this branch of atmospheric science; this is followed by a section on parameterisation and evaluation of kinetics data. A description of currently available on-line databases is provided. The final section contains a short description of some recent significant improvement in knowledge of rate constants for key reactions of interest in stratospheric and tropospheric chemistry.

引用

页码：6231 / 6246

页数：16

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