Is Dual Morphology of Rock-Salt Crystals Possible with a Single Additive? The Answer Is Yes, with Barbituric Acid

被引：15
作者：
Sen, Anik [1 ]
Ganguly, Bishwajit [1 ]
机构：
[1] Cent Salt & Marine Chem Res Inst, Analyt Discipline & Centralized Instrument Facil, Bhavnagar 364002, Gujarat, India
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 45期
关键词：
barbituric acid; crystal growth; density functional calculation; morphology; sodium chloride; DENSITY-FUNCTIONAL THERMOCHEMISTRY; GENERALIZED GRADIENT APPROXIMATION; POTASSIUM-CHLORIDE; CITRIC-ACID; 111; FACES; NACL; FORMAMIDE; GROWTH; HABIT; TAUTOMERISM;
D O I：
10.1002/anie.201206170
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Crystal face lift: Barbituric acid is shown to be a new crystal-habit modifier for sodium chloride crystals (see scheme). Two morphologies of salt crystals can be prepared separately with this new additive. It is of the few additives able to induce rhombic dodecahedron crystals for NaCl, and is required only a trace of amount, unlike other additives, such as glycine. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码：11279 / 11283
页数：5
相关论文
共 82 条
[1]   ACCURACY OF AN AUTOMATIC DIFFRACTOMETER . MEASUREMENT OF SODIUM CHLORIDE STRUCTURE FACTORS [J].
ABRAHAMS, SC ;
BERNSTEIN, JL .
ACTA CRYSTALLOGRAPHICA, 1965, 18 :926-+
[2]   Crystal structure of barbituric acid (1,4)-dioxane solvate at-173°C [J].
Al-Saqqar, S ;
Falvello, LR ;
Soler, T .
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2004, 34 (01) :61-65
[3]  
[Anonymous], MATERIALS STUDIO DMO
[4]  
[Anonymous], THESIS
[5]  
[Anonymous], GROWTH PERFECTION CR
[6]  
[Anonymous], CRYSTALLIZATION
[7]  
[Anonymous], 2004, GAUSSIAN03 REVISIONE
[8]  
[Anonymous], J AM CHEM SOC
[9]  
[Anonymous], SECOND SYMPOSIUM ON
[10]  
[Anonymous], 1783, CRISTALLOGRAPHIE
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