Bis[1-(2-hydroxyethyliminomethyl)-2-naphtholato-κ2N,O]nickel(II)

被引：15

作者：

Liu, Hui-Yan ^{[1
]}

Gao, Feng ^{[1
]}

Lu, Zai-Sheng ^{[1
]}

Wang, Hai-Ying ^{[1
]}

机构：

[1] Xuzhou Normal Univ, Dept Chem, Jiangsu 221116, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷

关键词：

D O I：

10.1107/S1600536806017041

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title nickel(II) complex, [Ni(C13H12NO2)(2)], has been synthesized by the reaction of a Schiff base ligand derived from 2-hydr-oxy-1-naphthaldehyde and 2-ethano-lamine with Ni(CH3COO)(2).4H(2)O. The asymmetric unit consists of half each of two independent mol-ecules which have similar geometries, with the Ni atom of each of the two neutral complex mol-ecules lying on an inversion centre. The coordination geometry around each Ni atom is square planar, with the two bidentate chelate Schiff base ligands coordinated through their imine N and phenol O atoms in a mutually trans configuration. The hydroxy O atoms do not coordinate to the Ni atom.

引用

页码：M1306 / M1308

页数：3

共 12 条

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