A 3D chiral Co(II) coordination polymer featuring unique self-interpenetrating topology

被引：10

作者：

Wang, Xiao-Fang ^{[1
]}

Liu, Yang ^{[1
]}

机构：

[1] Liaoning Univ, Pharmaceut Coll, Shenyang 110036, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 27卷

关键词：

Coordination polymer; Chirality; Hydrothermal synthesis; Crystal structure; Magnetism; METAL-ORGANIC FRAMEWORK; HOMOCHIRAL CRYSTALLIZATION; MAGNETIC-PROPERTIES; ACHIRAL LIGANDS; SINGLE-CRYSTAL; SEPARATION; NETWORKS; LAYER; ACID;

D O I：

10.1016/j.inoche.2012.10.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3D chiral coordination polymer, [Co-3(hfipbb)(2)(D-Hcam)(2)(hPP)(2)(H2O)(2)]center dot 2H(2)O (1) (H(2)hfipbb = 2,2-bis(4-carboxyphenyl)hexafluoropropane, D-H(2)cam=D-(+)camphoric acid, bpp=1,3-di(4-pyridyl)propane), has been hydrothermally synthesized, which features an interesting 6-connected self-interpenetrating (4(4).6(10).8) topological network. There exists predominantly antiferromagnetic interaction between the Co(II) centers in 1. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：76 / 78

页数：3

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