Synthesis, Crystal Structure and Catalytic Property of a Dioxomolybdenum(VI) Complex Derived From N′-[1-(2-Hydroxynaphthyl)ethylidene]-3-methylbenzohydrazide

被引：16

作者：

Xu, Wei-Xiu ^{[1
]}

Li, Wen-Hui ^{[1
]}

机构：

[1] Jingchu Univ Technol, Coll Chem Engn & Pharm, Jingmen 448000, Hubei, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 02期

关键词：

catalytic property; crystal structure; hydrazone; molybdenum complex; synthesis; HYDROGEN-PEROXIDE; OXIDATION; OXOMOLYBDENUM(VI); SULFIDES; LIGANDS; ACID;

D O I：

10.1080/15533174.2011.609511

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new dioxomolybdenum(VI) complex, [MoO2L(CH3OH)]center dot CH3OH, where L is the dianionic form of N'-[1-(2-hydroxynaphthyl)ethylidene]-3-methylbenzohydrazide, was prepared and structurally characterized by physicochemical and spectroscopic methods and single crystal X-ray determination. The complex is a mononuclear molybdenum compound. The Mo atom is in octahedral coordination. The catalytic property of the complex indicates that it is an effective catalyst for sulfoxidation.

引用

页码：160 / 164

页数：5

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