Promising long-lasting phosphor material: a novel metal-organic framework showing intriguing luminescent performance

被引:32
作者
Luo, Feng [1 ]
Sun, Gong-Ming [1 ]
Zheng, An-min [2 ]
Lian, Shi-xun [3 ]
Liu, Ying-liang [4 ]
Feng, Xue Feng [1 ]
Chu, Yue-ying [2 ]
机构
[1] E China Inst Technol, Coll Biol Chem & Mat Sci, Fuzhou 344000, Jiangxi, Peoples R China
[2] Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China
[3] Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China
[4] S China Agr Univ, Coll Sci, Guangzhou 510642, Guangdong, Peoples R China
关键词
PERSISTENT LUMINESCENCE; ENERGY-TRANSFER; PHOTOLUMINESCENCE; AFTERGLOW; FLUORESCENCE; MECHANISM; EMISSION;
D O I
10.1039/c2dt31879b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A distinct way to target long-lasting phosphors (LLPs) is disclosed. This new material is a metal-organic framework featuring a 1D zig-zag chain and 3D hydrogen bonded PtS net with three-fold interpenetration. It exhibits persistent luminescence lasting about 1 s which can be traced by the naked eye. The green persistent luminescence is exclusively due to emission from multiple triplet excited states. In this way, LLP can be easily achieved by using a simple hydrothermal synthesis without any codopant that in nature is responsible for well-known inorganic LLPs.
引用
收藏
页码:13280 / 13283
页数:4
相关论文
共 48 条
  • [1] Luminescent metal-organic frameworks
    Allendorf, M. D.
    Bauer, C. A.
    Bhakta, R. K.
    Houk, R. J. T.
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) : 1330 - 1352
  • [2] Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations
    An, Jihyun
    Shade, Chad M.
    Chengelis-Czegan, Demetra A.
    Petoud, Stephane
    Rosi, Nathaniel L.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) : 1220 - 1223
  • [3] TOPOS3.2:: A new version of the program package for multipurpose crystal-chemical analysis
    Blatov, VA
    Shevchenko, AP
    Serezhkin, VN
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2000, 33 : 1193 - 1193
  • [4] Formulation of phosphorescence mechanisms in inorganic solids based on a new model of defect conglomeration
    Clabau, F.
    Rocquefelte, X.
    Le Mercier, T.
    Deniard, P.
    Jobic, S.
    Whangbo, M-H.
    [J]. CHEMISTRY OF MATERIALS, 2006, 18 (14) : 3212 - 3220
  • [5] Mechanism of phosphorescence appropriate for the long-lasting phosphors Eu2+-doped SrAl2O4 with codopants Dy3+ and B3+
    Clabau, F
    Rocquefelte, X
    Jobic, S
    Deniard, P
    Whangbo, MH
    Garcia, A
    Le Mercier, T
    [J]. CHEMISTRY OF MATERIALS, 2005, 17 (15) : 3904 - 3912
  • [6] Postsynthetic Methods for the Functionalization of Metal-Organic Frameworks
    Cohen, Seth M.
    [J]. CHEMICAL REVIEWS, 2012, 112 (02) : 970 - 1000
  • [7] A Luminescent Mixed-Lanthanide Metal-Organic Framework Thermometer
    Cui, Yuanjing
    Xu, Hui
    Yue, Yanfeng
    Guo, Zhiyong
    Yu, Jiancan
    Chen, Zhenxia
    Gao, Junkuo
    Yang, Yu
    Qian, Guodong
    Chen, Banglin
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (09) : 3979 - 3982
  • [8] Luminescent Functional Metal-Organic Frameworks
    Cui, Yuanjing
    Yue, Yanfeng
    Qian, Guodong
    Chen, Banglin
    [J]. CHEMICAL REVIEWS, 2012, 112 (02) : 1126 - 1162
  • [9] Nanoprobes with near-infrared persistent luminescence for in vivo imaging
    de Chermont, Quentin le Masne
    Chaneac, Corinne
    Seguin, Johanne
    Pelle, Fabienne
    Maitrejean, Serge
    Jolivet, Jean-Pierre
    Gourier, Didier
    Bessodes, Michel
    Scherman, Daniel
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2007, 104 (22) : 9266 - 9271
  • [10] Structure and white luminescence of Eu-activated (Ba,Sr)13-XAl22-2xSi10+2xO66 materials
    Denis, Gregoire
    Deniard, Philippe
    Gautron, Eric
    Clabau, Frederic
    Garcia, Alain
    Jobic, Stephane
    [J]. INORGANIC CHEMISTRY, 2008, 47 (10) : 4226 - 4235