A direct reaction approach for the synthesis of zeolitic imidazolate frameworks: template and temperature mediated control on network topology and crystal size

被引：58

作者：

Lanchas, Monica ^{[1
]}

Vallejo-Sanchez, Daniel ^{[1
]}

Beobide, Garikoitz ^{[1
]}

Castillo, Oscar ^{[1
]}

Aguayo, Andres T. ^{[2
]}

Luque, Antonio ^{[1
]}

Roman, Pascual ^{[1
]}

机构：

[1] Univ Basque Country, Dept Quim Inorgan, Fac Ciencia & Tecnol, UPV EHU, E-48080 Bilbao, Spain

[2] Univ Basque Country, Dept Ingn Quim, Fac Ciencia & Tecnol, UPV EHU, E-48080 Bilbao, Spain

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 79期

关键词：

METAL-ORGANIC FRAMEWORKS; SOLVENT-FREE SYNTHESIS; AZOLATE FRAMEWORKS; COBALT; CO2;

D O I：

10.1039/c2cc34787c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The direct acid-base reaction between ZnO/CoO/Co(OH)(2) and imidazolic ligands under moderate heating (100-160 degrees C), in a closed vessel, leads to the generation of the corresponding zinc/cobalt-imidazolates in a high yield (87-97%) in which network topology is controlled by the addition of small amounts of structure directing agents. Moreover, the fine tuning of the thermal process at the synthetic stage permits us to increase the crystal size, and even to grow X-ray quality single crystals.

引用

页码：9930 / 9932

页数：3

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