Cavity ring-down spectroscopy of CO2 overtone bands near 830 nm

被引:12
作者
Tan, Y. [1 ]
Zhao, X. -Q. [1 ]
Liu, A-W [1 ,2 ]
Hu, S. -M. [1 ]
Lyulin, O. M. [3 ]
Tashkun, S. A. [3 ,4 ]
Perevalov, V. I. [3 ]
机构
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, IChem Ctr, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Synerget Innovat Ctr Quantum Informat & Quantum P, Hefei 230026, Peoples R China
[3] Russian Acad Sci, Lab Theoret Spect, VE Zuev Inst Atmospher Opt, Siberian Branch, Tomsk 634021, Russia
[4] Tomsk State Univ, Lab Quantum Mech Mol & Radiat Proc, Tomsk 634050, Russia
关键词
Carbon dioxide; Cavity ring down spectroscopy; Vibration-rotation; Line positions; Line intensities; Effective dipole moment parameters; CARBON-DIOXIDE; LINE-INTENSITIES; (CO2)-C-12; TRANSITIONS; EDITION;
D O I
10.1016/j.jqsrt.2015.06.010
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Three bands 4003i-00001 (i=2, 3, 4) of the Fermi pentad of (CO2)-C-12-O-16 near 830 nm have been recorded with a continuous-wave cavity ring down spectrometer. A sensitivity at the 5 x 10(-11) cm(-1) level allowed us to obtain line positions and intensities of these very weak bands. The measured line intensities of these three bands together with those published for the 10051-00001 and 10052-00001 bands were used to obtain the effective dipole moment parameters of (CO2)-C-12-O-16 u for the Delta P=17 series of transitions, where P=2V(1) + V-2 + 3V(3) is a polyad number (V-1 (i=1, 2, 3) are vibrational quantum numbers). Comparisons of the measured line positions and intensities of the 4003i-00001 (i = 2, 3,4) bands to those from the AMES and GEISA line lists are given. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:22 / 27
页数:6
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