Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions between Sulfamates and Potassium Boc-Protected Aminomethyltrifluoroborates

被引：39

作者：

Molander, Gary A. ^{[1
]}

Shin, Inji ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Roy & Diana A Vagelos Labs, Philadelphia, PA 19104 USA

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 10期

关键词：

MESYLATED PHENOL DERIVATIVES; ARYL TOSYLATES;

D O I：

10.1021/ol401021x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sulfamates were studied as the electrophilic partners in the palladium-catalyzed Suzuki-Miyaura cross-coupling reaction with potassium Boc-protected primary and secondary aminomethyltrifluoroborates. A broad range of substrates was successfully coupled to provide the desired products. Complex molecules containing a new carbon-carbon bond and an aminomethyl moiety could be prepared through this developed method.

引用

页码：2534 / 2537

页数：4

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