Application of Mass Spectrometry in the Synthesis and Characterization of Metal Nanoclusters

被引：56

作者：

Lu, Yizhong ^{[1
]}

Chen, Wei ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electoanalyt Chem, Changchun 130022, Jilin, Peoples R China

来源：

ANALYTICAL CHEMISTRY | 2015年 / 87卷 / 21期

基金：

中国国家自然科学基金;

关键词：

GOLD NANOCLUSTERS; KDA GOLD; CRYSTAL-STRUCTURE; CLUSTER COMPOUNDS; SIZE; IDENTIFICATION; GROWTH; NANOPARTICLES; CONVERSION; TRANSITION;

D O I：

10.1021/acs.analchem.5b00848

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In recent years, mass spectrometry has been widely used in the characterization of metal nanoclusters. In this Feature, we first give an introductory tutorial on mass spectrometry and then highlight the versatile applications of mass spectrometry in accurately analyzing core size, atom-level composition, charge states, etc. of metal nanoclusters and size evolution during synthesis. Finally, some perspectives on the future applications of mass spectrometry in nanocluster research are given.

引用

页码：10659 / 10667

页数：9

共 91 条

[1] Neat and Complete: Thiolate-Ligand Exchange on a Silver Molecular Nanoparticle [J].

AbdulHalim, Lina G. ;

Kothalawala, Nuwan ;

Sinatra, Lutfan ;

Dass, Amala ;

Bakr, Osman M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (45) :15865-15868

[2] A scalable synthesis of highly stable and water dispersible Ag44(SR)30 nanoclusters [J].

AbdulHalim, Lina G. ;

Ashraf, Sumaira ;

Katsiev, Khabiboulakh ;

Kirmani, Ahmad R. ;

Kothalawala, Nuwan ;

Anjum, Dalaver H. ;

Abbas, Sikandar ;

Amassian, Aram ;

Stellacci, Francesco ;

Dass, Amala ;

Hussain, Irshad ;

Bakr, Osman M. .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (35) :10148-10154

[3] Critical sizes in the growth of Au clusters [J].

Alvarez, MM ;

Khoury, JT ;

Schaaff, TG ;

Shafigullin, M ;

Vezmar, I ;

Whetten, RL .

CHEMICAL PHYSICS LETTERS, 1997, 266 (1-2) :91-98

[4] High-resolution time-of-flight mass spectra of alkanethiolate-coated gold nanocrystals [J].

Arnold, RJ ;

Reilly, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (07) :1528-1532

[5]

Ashcroft A.E., 1997, Ionization Methods in Organic Mass Spectrometry

[6] SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].

BRUST, M ;

WALKER, M ;

BETHELL, D ;

SCHIFFRIN, DJ ;

WHYMAN, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802

[7] SYNTHESIS AND REACTIONS OF FUNCTIONALIZED GOLD NANOPARTICLES [J].

BRUST, M ;

FINK, J ;

BETHELL, D ;

SCHIFFRIN, DJ ;

KIELY, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) :1655-1656

[8] Chemistry and properties of nanocrystals of different shapes [J].

Burda, C ;

Chen, XB ;

Narayanan, R ;

El-Sayed, MA .

CHEMICAL REVIEWS, 2005, 105 (04) :1025-1102

[9] Ubiquitous 8 and 29 kDa gold: Alkanethiolate cluster compounds: Mass-spectrometric determination of molecular formulas and structural implications [J].

Chaki, Nirmalya K. ;

Negishi, Yuichi ;

Tsunoyama, Hironori ;

Shichibu, Yukatsu ;

Tsukuda, Tatsuya .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (27) :8608-+

[10] Gold nanoelectrodes of varied size: Transition to molecule-like charging [J].

Chen, SW ;

Ingram, RS ;

Hostetler, MJ ;

Pietron, JJ ;

Murray, RW ;

Schaaff, TG ;

Khoury, JT ;

Alvarez, MM ;

Whetten, RL .

SCIENCE, 1998, 280 (5372) :2098-2101

← 1 2 3 4 5 6 7 8 9 10 →