Synthesis and structural characterization of [Na2M(C5O5)2(H2O)2]•4H2O (M = NiII, CuII)

被引：40
|
作者：
Wang, CC [1 ]
Yang, CH
Lee, GH
机构：
[1] Soochow Univ, Dept Chem, Taipei 11102, Taiwan
[2] Natl Taiwan Univ, Int Ctr, Taipei 10764, Taiwan
来源：
INORGANIC CHEMISTRY | 2002年 / 41卷 / 04期
关键词：
D O I：
10.1021/ic0108538
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this work, the anionic building blocks [M( C5O5)(2)(H2O2)(2)](2-) (M = Ni, Cu) are synthesized easily, and their structures are unique and interesting in the coordination chemistry of croconate ligand (C5O52-) with the first transition metal. The [M(C5O5)(2)(H2O2)(2)](2-) moieties act as a dianionic template, and sodium acts as interconnecting cations to build up a three-dimensional framework.
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页码：1015 / +
页数：5
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