Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy

被引：289

作者：

Mudiyanselage, Kumudu ^{[1
]}

Senanayake, Sanjaya D. ^{[1
]}

Feria, Leticia ^{[2
]}

Kundu, Shankhamala ^{[1
]}

Baber, Ashleigh E. ^{[1
]}

Graciani, Jesus ^{[1
,2
]}

Vidal, Alba B. ^{[1
]}

Agnoli, Stefano ^{[1
]}

Evans, Jaime ^{[3
]}

Chang, Rui ^{[4
]}

Axnanda, Stephanus ^{[5
]}

Liu, Zhi ^{[5
]}

Sanz, Javier F. ^{[2
]}

Liu, Ping ^{[1
]}

Rodriguez, Jose A. ^{[1
]}

Stacchiola, Dario J. ^{[1
]}

机构：

[1] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

[2] Univ Seville, Dept Quim Fis, E-41012 Seville, Spain

[3] Cent Univ Venezuela, Fac Ciencias, Caracas 1020A, Venezuela

[4] Shanghai Inst Microsyst & Informat Technol, Shanghai 200050, Peoples R China

[5] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 19期

关键词：

ceria; heterogeneous catalysis; nanocatalysis; surface chemistry; watergas shift reaction; SURFACE-CHEMISTRY; MECHANISM; CO2; PHOTOEMISSION; CEOX/CU(111); ADSORPTION; OXIDATION; AU(111); COPPER;

D O I：

10.1002/anie.201210077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Where oxide and metals meet: The activation of an efficient associative mechanistic pathway for the water-gas shift reaction by an oxide-metal interface leads to an increase in the catalytic activity of nanoparticles of ceria deposited on Cu(111) or Au(111) by more than an order of magnitude (see graph). In situ experiments demonstrated that a carboxy species formed at the metal-oxide interface is the critical intermediate in the reaction. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5101 / 5105

页数：5

共 50 条

[31] Exploring the CO2 reduction reaction mechanism on Pt/TiO2 with the ambient-pressure X-ray photoelectron spectroscopy
Zhang, Huan
Xie, Lei
Huang, Chaoqin
Ren, Zhiguo
Wang, Hongbing
Hu, Jinping
Zhang, Hui
Jiang, Zheng
Song, Fei
[J]. APPLIED SURFACE SCIENCE, 2021, 568
[32] In situ quantitative analysis of electrochemical oxide film development on metal surfaces using ambient pressure X-ray photoelectron spectroscopy: Industrial alloys
Larsson, Alfred
Simonov, Konstantin
Eidhagen, Josefin
Grespi, Andrea
Yue, Xiaoqi
Tang, Huajie
Delblanc, Anna
Scardamaglia, Mattia
Shavorskiy, Andrey
Pan, Jinshan
Lundgren, Edvin
[J]. APPLIED SURFACE SCIENCE, 2023, 611
[33] Using "Tender" X-ray Ambient Pressure X-Ray Photoelectron Spectroscopy as A Direct Probe of Solid-Liquid Interface
Axnanda, Stephanus
Crumlin, Ethan J.
Mao, Baohua
Rani, Sana
Chang, Rui
Karlsson, Patrik G.
Edwards, Marten O. M.
Lundqvist, Mans
Moberg, Robert
Ross, Phil
Hussain, Zahid
Liu, Zhi
[J]. SCIENTIFIC REPORTS, 2015, 5
[34] Revealing the Surface Species Evolution on Low-loading Platinum in an Electrochemical Redox Reaction by Operando Ambient-Pressure X-ray Photoelectron Spectroscopy
Yang, Chueh-Cheng
Tsai, Meng-Hsuan
Yang, Zong-Ren
Tseng, Yuan-Chieh
Wang, Chia-Hsin
[J]. CHEMCATCHEM, 2023, 15 (12)
[35] In-situ characterization of water-gas shift catalysts using time-resolved X-ray diffraction
Rodriguez, Jose A.
Hanson, Jonathan C.
Wen, Wen
Wang, Xianqin
Brito, Joaquin L.
Martinez-Arias, Arturo
Fernandez-Garcia, Marcos
[J]. CATALYSIS TODAY, 2009, 145 (3-4) : 188 - 194
[36] Sub-nanosecond time-resolved ambient-pressure X-ray photoelectron spectroscopy setup for pulsed and constant wave X-ray light sources
Shavorskiy, Andrey
Neppl, Stefan
Slaughter, Daniel S.
Cryan, James P.
Siefermann, Katrin R.
Weise, Fabian
Lin, Ming-Fu
Bacellar, Camila
Ziemkiewicz, Michael P.
Zegkinoglou, Ioannis
Fraund, Matthew W.
Khurmi, Champak
Hertlein, Marcus P.
Wright, Travis W.
Huse, Nils
Schoenlein, Robert W.
Tyliszczak, Tolek
Coslovich, Giacomo
Robinson, Joseph
Kaindl, Robert A.
Rude, Bruce S.
Oelsner, Andreas
Maehl, Sven
Bluhm, Hendrik
Gessner, Oliver
[J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 2014, 85 (09)
[37] Water Reactivity on the LaCoO3 (001) Surface: An Ambient Pressure X-ray Photoelectron Spectroscopy Study
Stoerzinger, Kelsey A.
Hong, Wesley T.
Crumlin, Ethan J.
Bluhm, Hendrik
Biegalski, Michael D.
Shao-Horn, Yang
[J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (34) : 19733 - 19741
[38] Recycling of CO2: Probing the Chemical State of the Ni(111) Surface during the Methanation Reaction with Ambient-Pressure X-Ray Photoelectron Spectroscopy
Heine, Christian
Lechner, Barbara A. J.
Bluhm, Hendrik
Salmeron, Miquel
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (40) : 13246 - 13252
[39] CO2 Activation on Cobalt Surface in the Presence of H2O: An Ambient-Pressure X-ray Photoelectron Spectroscopy Study
Liu, Qiang
Han, Yong
Cai, Jun
Crumlin, Ethan J.
Li, Yimin
Liu, Zhi
[J]. CATALYSIS LETTERS, 2018, 148 (06) : 1686 - 1691
[40] Kinetics of the Thermal Oxidation of Ir(100) toward IrO2 Studied by Ambient-Pressure X-ray Photoelectron Spectroscopy
Novotny, Zbynek
Tobler, Benjamin
Artiglia, Luca
Fischer, Martin
Schreck, Matthias
Raabe, Joerg
Osterwalder, Juerg
[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2020, 11 (09) : 3601 - 3607

← 1 2 3 4 5 →