Studies Toward Communesin F: A Diels-Alder Approach

被引：24
作者：
Danielsson, Jakob [1 ]
Somfai, Peter [1 ,2 ]
机构：
[1] Lund Univ, Dept Chem, Ctr Anal & Synth, S-22100 Lund, Sweden
[2] Univ Tartu, Inst Technol, EE-50411 Tartu, Estonia
来源：
ORGANIC LETTERS | 2014年 / 16卷 / 03期
关键词：
BIOMIMETIC APPROACH; CONSTRUCTION; PEROPHORAMIDINE; ALKALOIDS;
D O I：
10.1021/ol403516s
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A Diels-Alder reaction is used as a key step in a synthetic study toward communesin F, in order to simultaneously introduce both of the all-carbon quaternary stereocenters with complete control of relative stereochemistry. Further manipulations of the cycloadduct, toward the hexacyclic core-structure of communesin F, are also disclosed.
引用
收藏
页码：784 / 787
页数：4
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