Studies Toward Communesin F: A Diels-Alder Approach

被引：24

作者：

Danielsson, Jakob ^{[1
]}

Somfai, Peter ^{[1
,2
]}

机构：

[1] Lund Univ, Dept Chem, Ctr Anal & Synth, S-22100 Lund, Sweden

[2] Univ Tartu, Inst Technol, EE-50411 Tartu, Estonia

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 03期

关键词：

BIOMIMETIC APPROACH; CONSTRUCTION; PEROPHORAMIDINE; ALKALOIDS;

D O I：

10.1021/ol403516s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Diels-Alder reaction is used as a key step in a synthetic study toward communesin F, in order to simultaneously introduce both of the all-carbon quaternary stereocenters with complete control of relative stereochemistry. Further manipulations of the cycloadduct, toward the hexacyclic core-structure of communesin F, are also disclosed.

引用

页码：784 / 787

页数：4

共 37 条

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