Investigation of the magnetic phase transition and magnetocaloric properties of the Mn2FeSbO6 ilmenite

被引：11
|
作者：
Hudl, M. [1 ]
Mathieu, R. [1 ]
Nordblad, P. [1 ]
Ivanov, S. A. [1 ,2 ]
Bazuev, G. V. [3 ]
Lazor, P. [4 ]
机构：
[1] Uppsala Univ, Dept Engn Sci, SE-75121 Uppsala, Sweden
[2] Karpov Inst Phys Chem, Dept Inorgan Mat, Moscow 105064, Russia
[3] Russian Acad Sci, Inst Solid State Chem, Ural Branch, Ekaterinburg 620999, Russia
[4] Uppsala Univ, Dept Earth Sci, SE-75236 Uppsala, Sweden
来源：
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS | 2013年 / 331卷
基金：
俄罗斯基础研究基金会; 瑞典研究理事会;
关键词：
Melanostibite; Magnetocaloric property; Magnetic phase transition; REFRIGERATION;
D O I：
10.1016/j.jmmm.2012.11.040
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The magnetic phase transition and magnetocaloric properties of both mineral and synthetic melanostibite Mn2FeSbO6 with ilmenite-type structure have been studied. Mn2FeSbO6 orders ferrimagnetically below 270 K and is found to undergo a second-order magnetic phase transition. The associated magnetic entropy change was found to be 1.7J/kg K for the mineral and 1.8J/kg K for the synthetic melanostibite for 5 T field change. For the synthetic Mn2FeSbO6 the adiabatic temperature change was estimated from magnetic- and specific heat measurements and amounts to 0.2 K in 1 T field change. Perspectives of the functional properties of Mn2FeSbO6-based materials are discussed. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：193 / 197
页数：5
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