Investigation of the magnetic phase transition and magnetocaloric properties of the Mn2FeSbO6 ilmenite

被引：11
作者：
Hudl, M. [1 ]
Mathieu, R. [1 ]
Nordblad, P. [1 ]
Ivanov, S. A. [1 ,2 ]
Bazuev, G. V. [3 ]
Lazor, P. [4 ]
机构：
[1] Uppsala Univ, Dept Engn Sci, SE-75121 Uppsala, Sweden
[2] Karpov Inst Phys Chem, Dept Inorgan Mat, Moscow 105064, Russia
[3] Russian Acad Sci, Inst Solid State Chem, Ural Branch, Ekaterinburg 620999, Russia
[4] Uppsala Univ, Dept Earth Sci, SE-75236 Uppsala, Sweden
来源：
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS | 2013年 / 331卷
基金：
俄罗斯基础研究基金会; 瑞典研究理事会;
关键词：
Melanostibite; Magnetocaloric property; Magnetic phase transition; REFRIGERATION;
D O I：
10.1016/j.jmmm.2012.11.040
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The magnetic phase transition and magnetocaloric properties of both mineral and synthetic melanostibite Mn2FeSbO6 with ilmenite-type structure have been studied. Mn2FeSbO6 orders ferrimagnetically below 270 K and is found to undergo a second-order magnetic phase transition. The associated magnetic entropy change was found to be 1.7J/kg K for the mineral and 1.8J/kg K for the synthetic melanostibite for 5 T field change. For the synthetic Mn2FeSbO6 the adiabatic temperature change was estimated from magnetic- and specific heat measurements and amounts to 0.2 K in 1 T field change. Perspectives of the functional properties of Mn2FeSbO6-based materials are discussed. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：193 / 197
页数：5
相关论文
共 25 条
  • [1] CRITERION FOR FERROMAGNETISM FROM OBSERVATIONS OF MAGNETIC ISOTHERMS
    ARROTT, A
    [J]. PHYSICAL REVIEW, 1957, 108 (06): : 1394 - 1396
  • [2] APPROXIMATE EQUATION OF STATE FOR NICKEL NEAR ITS CRITICAL TEMPERATURE
    ARROTT, A
    NOAKES, JE
    [J]. PHYSICAL REVIEW LETTERS, 1967, 19 (14) : 786 - &
  • [3] ON A GENERALISED APPROACH TO 1ST AND 2ND ORDER MAGNETIC TRANSITIONS
    BANERJEE, SK
    [J]. PHYSICS LETTERS, 1964, 12 (01): : 16 - 17
  • [4] High pressure synthesis and polymorphism of complex oxides Mn2BSbO6(B=Fe,V,Cr,Ga,Al)
    Bazuev, GV
    Golovkin, BG
    Lukin, NV
    Kadyrova, NI
    Zainulin, YG
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1996, 124 (02) : 333 - 337
  • [5] Theoretical aspects of the magnetocaloric effect
    de Oliveira, N. A.
    von Ranke, P. J.
    [J]. PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 2010, 489 (4-5): : 89 - 159
  • [6] Magnetocaloric effect around a magnetic phase transition
    de Oliveira, N. A.
    von Ranke, P. J.
    [J]. PHYSICAL REVIEW B, 2008, 77 (21):
  • [7] Mixed Magnetism for Refrigeration and Energy Conversion
    Dung, Nguyen H.
    Ou, Zhi Qiang
    Caron, Luana
    Zhang, Lian
    Thanh, Dinh T. Cam
    de Wijs, Gilles A.
    de Groot, Rob A.
    Buschow, K. H. Jurgen
    Bruck, Ekkes
    [J]. ADVANCED ENERGY MATERIALS, 2011, 1 (06) : 1215 - 1219
  • [8] The Magnetocaloric Effect and Magnetic Refrigeration Near Room Temperature: Materials and Models
    Franco, V.
    Blazquez, J. S.
    Ingale, B.
    Conde, A.
    [J]. ANNUAL REVIEW OF MATERIALS RESEARCH, VOL 42, 2012, 42 : 305 - 342
  • [9] Recent developments in magnetocaloric materials
    Gschneidner, KA
    Pecharsky, VK
    Tsokol, AO
    [J]. REPORTS ON PROGRESS IN PHYSICS, 2005, 68 (06) : 1479 - 1539
  • [10] Magnetic Materials and Devices for the 21st Century: Stronger, Lighter, and More Energy Efficient
    Gutfleisch, Oliver
    Willard, Matthew A.
    Bruck, Ekkes
    Chen, Christina H.
    Sankar, S. G.
    Liu, J. Ping
    [J]. ADVANCED MATERIALS, 2011, 23 (07) : 821 - 842
123