Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries

被引：401

作者：

Doe, Robert E. ^{[1
]}

Han, Ruoban ^{[1
]}

Hwang, Jaehee ^{[1
]}

Gmitter, Andrew J. ^{[1
]}

Shterenberg, Ivgeni ^{[2
]}

Yoo, Hyun Deog ^{[2
]}

Pour, Nir ^{[2
]}

Aurbach, Doron ^{[2
]}

机构：

[1] Pell Technol, Cambridge, MA 02139 USA

[2] Bar Ilan Univ, Dept Chem, IL-92100 Ramat Gan, Israel

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 02期

关键词：

STRUCTURAL-ANALYSIS; COMPLEXES;

D O I：

10.1039/c3cc47896c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein the first inorganic magnesium salt solution capable of highly reversible magnesium electrodeposition is presented. Synthesized by acid-base reaction of MgCl2 and Lewis acidic compounds such as AlCl3, this salt class demonstrates upwards of 99% Coulombic efficiency, deposition overpotential of <200 mV, and anodic stability of 3.1 V.

引用

收藏

页码：243 / 245

页数：3

相关论文

共 11 条

[1] Prototype systems for rechargeable magnesium batteries [J].

Aurbach, D ;

Lu, Z ;

Schechter, A ;

Gofer, Y ;

Gizbar, H ;

Turgeman, R ;

Cohen, Y ;

Moshkovich, M ;

Levi, E .

NATURE, 2000, 407 (6805) :724-727

[2] Electrolyte solutions for rechargeable magnesium batteries based on organomagnesium chloroaluminate complexes [J].

Aurbach, D ;

Gizbar, H ;

Schechter, A ;

Chusid, O ;

Gottlieb, HE ;

Gofer, Y ;

Goldberg, I .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (02) :A115-A121

[3]

Doe R . E., 2013, International Pat. App., Patent No. [PCT/US2012/071350, 2012071350]

[4] The electrolysis of Grignard solution [J].

Gaddum, LW ;

French, HE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1927, 49 :1295-1299

[5] NONAQUEOUS ELECTROCHEMISTRY OF MAGNESIUM - APPLICATIONS TO ENERGY-STORAGE [J].

GREGORY, TD ;

HOFFMAN, RJ ;

WINTERTON, RC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (03) :775-780

[6] Study on electrochemically deposited Mg metal [J].

Matsui, Masaki .

JOURNAL OF POWER SOURCES, 2011, 196 (16) :7048-7055

[7] Electrolyte roadblocks to a magnesium rechargeable battery [J].

Muldoon, John ;

Bucur, Claudiu B. ;

Oliver, Allen G. ;

Sugimoto, Tsuyoshi ;

Matsui, Masaki ;

Kim, Hee Soo ;

Allred, Gary D. ;

Zajicek, Jaroslav ;

Kotani, Yukinari .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (03) :5941-5950

[8] Structural Analysis of Electrolyte Solutions for Rechargeable Mg Batteries by Stereoscopic Means and DFT Calculations [J].

Pour, Nir ;

Gofer, Yossi ;

Major, Dan T. ;

Aurbach, Doron .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (16) :6270-6278

[9] Structural analysis of electrolyte solutions comprising magnesium-aluminate chloro-organic complexes by Raman spectroscopy [J].

Vestfried, Yulia ;

Chusid, Orit ;

Goffer, Yossi ;

Aped, Pinchas ;

Aurbach, Doron .

ORGANOMETALLICS, 2007, 26 (13) :3130-3137

[10] Microelectrode studies of reversible Mg deposition in THF solutions containing complexes of alkylaluminum chlorides and dialkylmagnesium [J].

Viestfrid, Y ;

Levi, MD ;

Gofer, Y ;

Aurbach, D .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 576 (02) :183-195