Spherical cluster comprising a four- and six-membered-ring motif

被引：55

作者：

Johnson, BP

Dielmann, F

Balázs, G

Sierka, M

Scheer, M ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

[2] Humboldt Univ, Inst Chem, D-10099 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 15期

关键词：

cluster compounds; density functional calculations; fullerenes; phosphorus; tantalum;

D O I：

10.1002/anie.200503511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Magic ball: A spherical aggregate containing a core of 32 inorganic atoms (see structure) was prepared by coordination of a cyclo-P4 tantalum complex to copper(I) chloride. The phosphorus/copper core exhibits an arrangement of alternating four- and six-membered rings, which are reminiscent of the hypothetical Oh-symmetric fullerene C32. (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2473 / 2475

页数：3

共 30 条

[1] ELECTRONIC-STRUCTURE CALCULATIONS ON WORKSTATION COMPUTERS - THE PROGRAM SYSTEM TURBOMOLE [J].

AHLRICHS, R ;

BAR, M ;

HASER, M ;

HORN, H ;

KOLMEL, C .

CHEMICAL PHYSICS LETTERS, 1989, 162 (03) :165-169

[2] ENERGY-ADJUSTED ABINITIO PSEUDOPOTENTIALS FOR THE 2ND AND 3RD ROW TRANSITION-ELEMENTS [J].

ANDRAE, D ;

HAUSSERMANN, U ;

DOLG, M ;

STOLL, H ;

PREUSS, H .

THEORETICA CHIMICA ACTA, 1990, 77 (02) :123-141

[3]

[Anonymous], 2015, Acta Crystallogr., V71, P3

[4]

Bai J., 2002, Angew. Chem, V114, P820

[5] Synthesis of inorganic fullerene-like molecules [J].

Bai, JF ;

Virovets, AV ;

Scheer, M .

SCIENCE, 2003, 300 (5620) :781-783

[6]

Bai JF, 2002, ANGEW CHEM INT EDIT, V41, P1737, DOI 10.1002/1521-3773(20020517)41:10<1737::AID-ANIE1737>3.0.CO

[7]

2-4

[8] Reactions of transition metal complexes with fullerenes (C60, C70, etc.) and related materials [J].

Balch, AL ;

Olmstead, MM .

CHEMICAL REVIEWS, 1998, 98 (06) :2123-2165

[9] DENSITY-FUNCTIONAL EXCHANGE-ENERGY APPROXIMATION WITH CORRECT ASYMPTOTIC-BEHAVIOR [J].

BECKE, AD .

PHYSICAL REVIEW A, 1988, 38 (06) :3098-3100

[10] CYCLOBUTADIENE COMPLEXES AND THE ROLE OF LIGAND NON-BONDING OR PERIPHERAL ORBITALS [J].

CHU, SY ;

HOFFMANN, R .

JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (08) :1289-1297

← 1 2 3 →