Synthesis, crystal growth and characterization of a semiorganic material: Thiosemicarbazide potassium chloride

被引：9

作者：

Chandrasekaran, J. ^{[1
]}

Ilayabarathi, P. ^{[2
]}

Maadeswaran, P. ^{[3
]}

Balaprabhakaran, S. ^{[1
]}

Sathishkumar, K. ^{[1
]}

Babu, B. ^{[1
]}

机构：

[1] Sri Ramakrishna Mission Vidyalaya Coll Arts & Sci, Dept Phys, Coimbatore 641020, Tamil Nadu, India

[2] Bharathiar Univ, Ctr Res & Dev, Coimbatore 641046, Tamil Nadu, India

[3] KS Rangasamy Coll Technol, Dept Phys, Tiruchengode 637215, Tamil Nadu, India

来源：

OPTIK | 2013年 / 124卷 / 01期

关键词：

Thiosemicarbazide potassium chloride; Infrared spectrum; Optical transmission spectrum; Thermal analysis and microhardness; NONLINEAR-OPTICAL MATERIAL; CADMIUM CHLORIDE; SINGLE-CRYSTALS; PURE;

D O I：

10.1016/j.ijleo.2011.11.023

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Thiosemicarbazide potassium chloride (K(NH2NHCSNH2)Cl center dot H2O) (TSCPC) is one of the potential semiorganic materials for many applications. The crystal growth of TSCPC by slow evaporation method at ambient temperature and its dimension was found to be (5 mm x 3 mm x 2 mm). The grown crystals where characterized by Fourier transform infrared spectroscopic (FT IR) analysis to find the different modes of vibration due to various functional groups present in TSCPC. The powder X-ray diffraction pattern of the grown crystal has been studied. Thermal stability of the grown crystal was identified at 185 degrees C by using TGA/DTA. The dielectric constant of the crystal was studied as a function of temperature with frequency and the results are discussed. The mechanical property of the grown crystal has been studied using Vicker's microhardness tester. The optical transmission spectrum was investigated to study its linear optical properties using UV-vis spectrophotometer. (C) 2011 Elsevier GmbH. All rights reserved,

引用

页码：31 / 34

页数：4

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