Simple, commercially available borane adducts, H3B center dot THF and H3B center dot SMe2, have been used to catalyse the hydroboration of alkynes and alkenes with pinacolborane to give the alkenyl and alkyl boronic esters, respectively. Alkynes and terminal alkenes underwent highly regioselective hydroboration to give the linear boronic ester products. Good functional group tolerance was observed for substrates bearing ester, amine, ether and halide substituents. This catalytic process shows comparable reactivity to transition-metal-catalysed hydroboration protocols.
机构:
Univ Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
Univ Montpellier 2, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, FranceUniv Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
Barbeyron, Renaud
;
Benedetti, Erica
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ESPCI ParisTech CNRS PSL Res Univ, UMR 8231, Inst Chem Biol & Innovat CBI, Chim Organ Lab, F-75231 Paris 05, FranceUniv Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
Benedetti, Erica
;
Cossy, Janine
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ESPCI ParisTech CNRS PSL Res Univ, UMR 8231, Inst Chem Biol & Innovat CBI, Chim Organ Lab, F-75231 Paris 05, FranceUniv Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
Cossy, Janine
;
Vasseur, Jean-Jacques
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机构:
Univ Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
Univ Montpellier 2, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, FranceUniv Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
Vasseur, Jean-Jacques
;
Arseniyadis, Stellios
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机构:
ESPCI ParisTech CNRS PSL Res Univ, UMR 8231, Inst Chem Biol & Innovat CBI, Chim Organ Lab, F-75231 Paris 05, FranceUniv Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
机构:
Univ Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
Univ Montpellier 2, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, FranceUniv Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
Barbeyron, Renaud
;
Benedetti, Erica
论文数: 0引用数: 0
h-index: 0
机构:
ESPCI ParisTech CNRS PSL Res Univ, UMR 8231, Inst Chem Biol & Innovat CBI, Chim Organ Lab, F-75231 Paris 05, FranceUniv Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
Benedetti, Erica
;
Cossy, Janine
论文数: 0引用数: 0
h-index: 0
机构:
ESPCI ParisTech CNRS PSL Res Univ, UMR 8231, Inst Chem Biol & Innovat CBI, Chim Organ Lab, F-75231 Paris 05, FranceUniv Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
Cossy, Janine
;
Vasseur, Jean-Jacques
论文数: 0引用数: 0
h-index: 0
机构:
Univ Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
Univ Montpellier 2, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, FranceUniv Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France
Vasseur, Jean-Jacques
;
Arseniyadis, Stellios
论文数: 0引用数: 0
h-index: 0
机构:
ESPCI ParisTech CNRS PSL Res Univ, UMR 8231, Inst Chem Biol & Innovat CBI, Chim Organ Lab, F-75231 Paris 05, FranceUniv Montpellier I, UMR CNRS 5247, Inst Biomol Max Mousseron, F-34095 Montpellier, France