Even-parity auto-ionizing states of iridium I observed by resonance laser ionization spectroscopy

被引:3
作者
Philipsen, V [1 ]
Bastiaansen, J [1 ]
Lievens, P [1 ]
Vandeweert, E [1 ]
Silverans, RE [1 ]
机构
[1] Katholieke Univ Leuven, Lab Vaste Stoffys & Magnetisme, B-3001 Louvain, Belgium
关键词
iridium; resonance ionization spectroscopy; auto-ionizing states; atomic spectroscopy;
D O I
10.1016/S0584-8547(01)00360-3
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Auto-ionizing states of neutral iridium were observed in the continuum structure near the first ionization limit using one-color and two-color two-step resonance laser ionization spectroscopy. The total angular momentum of 20 even-parity auto-ionizing states could be determined from a combined analysis of the two-color spectra obtained with ionization schemes using intermediate states with different total angular momentum. Double-resonant ionization schemes were evaluated by fluence-dependence measurements, and photo-ionization cross-sections for resonant ionization transitions were determined. We could also identify several high-lying members of ns, np and nd Rydberg series converging to the first ionization limit of the atom. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:95 / 107
页数:13
相关论文
共 13 条
[1]   SIMULTANEOUS DUAL-ELEMENT ANALYSES OF REFRACTORY-METALS IN NATURALLY-OCCURRING MATRICES USING RESONANCE IONIZATION OF SPUTTERED ATOMS [J].
CALAWAY, WF ;
WIENS, RC ;
BURNETT, DS ;
PELLIN, MJ ;
GRUEN, DM .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1995, 13 (03) :1310-1315
[2]  
Charles W.R.B., 1962, NBS Monograph
[3]   First ionization potentials of osmium and iridium determined by mass-analyzed double-resonance field-ionization spectroscopy [J].
Colarusso, P ;
LebeaultDorget, MA ;
Simard, B .
PHYSICAL REVIEW A, 1997, 55 (02) :1526-1529
[4]  
Cowan R. D., 1981, The theory of atomic structure and spectra, V3
[5]  
Demtroder W., 1981, LASER SPECTROSCOPY B, DOI DOI 10.1007/978-3-662-08257-7
[6]  
Garrison BJ, 1998, RAPID COMMUN MASS SP, V12, P1266, DOI 10.1002/(SICI)1097-0231(19980930)12:18<1266::AID-RCM323>3.0.CO
[7]  
2-I
[8]  
Letokhov V.S., 1987, Laser Photoionization Spectroscopy
[9]   Resonant photoionization of Ni I into autoionizing states [J].
Lievens, P ;
Vandeweert, E ;
Thoen, P ;
Silverans, RE .
PHYSICAL REVIEW A, 1996, 54 (03) :2253-2259
[10]  
MOORE CE, 1971, NSRDS NBS, V32, P177