Metalloporphyrin molecular sieves based on tin(IV)porphyrin phenolates

被引：41
作者：
Fallon, GD
Lee, MAP
Langford, SJ [1 ]
Nichols, PJ
机构：
[1] Monash Univ, Dept Chem, Clayton, Vic 3800, Australia
[2] Monash Univ, Ctr Green Chem, Clayton, Vic 3800, Australia
来源：
ORGANIC LETTERS | 2002年 / 4卷 / 11期
关键词：
D O I：
10.1021/ol025935u
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] The crystal and molecular structures of two six-coordinate tin(IV)porphyrin phenolate complexes show that infinite cylindrical channels of uniform pore dimension are formed along the crystallographic c-direction. The underlying recognition event responsible for the porosity is an extremely tight intermeshing of the meso-tolyl units between layers which is a result of Sn-(OH)-H-... interactions. Thermogravimetric analysis and differential scanning calorimetry have been used to characterize the sieve-like materials.
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页码：1895 / 1898
页数：4
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