Nickel-catalysed novel β,γ-unsaturated nitrile synthesis

被引：42

作者：

Tang, Shan ^{[1
]}

Liu, Chao ^{[1
]}

Lei, Aiwen ^{[1
,2
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan, Peoples R China

[2] Peking Univ, Lab Chem Genom, Sch Chem Biol & Biotechnol, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 24期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

INTERNAL DOUBLE-BOND; ALLYLIC CARBONATES; ALPHA-HALOESTER; METAL; HETEROCYCLES; CYCLIZATION; CONVERSION; CYANATION;

D O I：

10.1039/c3cc00029j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Through a nickel-catalysed Heck-type reaction, a direct coupling of alkenes with alpha-cyano alkyl bromides was achieved. This procedure provides a novel way for the synthesis of beta,gamma-unsaturated nitriles.

引用

页码：2442 / 2444

页数：3

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