Nickel-catalysed novel β,γ-unsaturated nitrile synthesis

被引：41
|
作者：
Tang, Shan [1 ]
Liu, Chao [1 ]
Lei, Aiwen [1 ,2 ]
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan, Peoples R China
[2] Peking Univ, Lab Chem Genom, Sch Chem Biol & Biotechnol, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 24期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
INTERNAL DOUBLE-BOND; ALLYLIC CARBONATES; ALPHA-HALOESTER; METAL; HETEROCYCLES; CYCLIZATION; CONVERSION; CYANATION;
D O I：
10.1039/c3cc00029j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Through a nickel-catalysed Heck-type reaction, a direct coupling of alkenes with alpha-cyano alkyl bromides was achieved. This procedure provides a novel way for the synthesis of beta,gamma-unsaturated nitriles.
引用
收藏
页码：2442 / 2444
页数：3
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