Four- and five-membered cobaltacycles by regioselective cyclometallation of benzyl sulfide derivatives via Co(v) intermediates

被引：18

作者：

Beck, Robert ^{[1
]}

Frey, Markus ^{[1
]}

Camadanli, Sebnem ^{[1
]}

Klein, Hans-Friedrich ^{[1
]}

机构：

[1] Tech Univ Darmstadt, Eduard Zintl Inst Anorgan & Phys Chem, D-64287 Darmstadt, Germany

来源：

DALTON TRANSACTIONS | 2008年 / 37期

关键词：

D O I：

10.1039/b810272d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

C-H activation through the coordination of a benzyl sulfide anchoring group with a C-S bond cleavage at a Co(V) center constitutes a regiospecific access to four- and five-membered metallacycles under mild conditions.

引用

页码：4981 / 4983

页数：3

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