Vanadium catalyzed aerobic carbon-carbon cleavage

被引：63

作者：

Amadio, Emanuele ^{[1
]}

Di Lorenzo, Rosalia ^{[1
]}

Zonta, Cristiano ^{[1
,2
]}

Licini, Giulia ^{[1
,2
,3
]}

机构：

[1] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy

[2] CIRCC, I-70126 Bari, Italy

[3] Univ Libre Bruxelles, Ecole Polytechn Bruxelles, Engn Mol NanoSyst, B-1050 Brussels, Belgium

来源：

COORDINATION CHEMISTRY REVIEWS | 2015年 / 301卷

关键词：

Vanadium complexes; Vanadium catalyzed oxidations; Carbon-carbon oxidative 1,2-diol cleavage; Aerobic oxidative C-C bond cleavage; Lignin and lignin model oxidation; Carbohydrates aerobic and anaerobic oxidation; C-C BOND; OXIDATIVE CLEAVAGE; VICINAL DIOLS; VIC-DIOLS; ORGANIC-COMPOUNDS; MOLECULAR-OXYGEN; QUINQUEVALENT VANADIUM; DITERTIARY GLYCOLS; ELECTRON-TRANSFER; MILD CONDITIONS;

D O I：

10.1016/j.ccr.2015.06.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In recent years, the use of vanadium complexes as catalysts and air or oxygen as oxidants has emerged as a new method for the effective oxidative carbon-carbon bond cleavage in a series of substrates, including 1,2-diols and alpha-hydroxy ethers. In addition to the advantageous use as a synthetic tool, vanadium catalyzed aerobic C-C bond cleavage becomes even more appealing if applied to the degradation of lignocellulosic biomass and in particular in the oxidative depolymerization/degradation of lignin or cellulose. In this review, this chemistry, the most recent advances and the role played by homogeneous vanadium complexes are presented and discussed. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：147 / 162

页数：16

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