Thiophene anchored naphthalene derivative: Cr3+ selective turn-on fluorescent probe for living cell imaging

被引:24
作者
Das, Sudipta [1 ]
Sahana, Animesh [1 ]
Banerjee, Arnab [1 ]
Lohar, Sisir [1 ]
Guha, Subarna [1 ]
Matalobos, Jesus Sanmartin [2 ]
Das, Debasis [1 ]
机构
[1] Fac Quim, Dept Quim Inorgan, Santiago De Compostela 15782, Spain
[2] Univ Burdwan, Dept Chem, Burdwan 713104, W Bengal, India
关键词
SENSORS; DESIGN; CHROMIUM(III); ENHANCEMENT; CHEMOSENSOR; CR(III); BINDING;
D O I
10.1039/c2ay25384d
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A naphthalene-based thiophene derivative (L) can act as a Cr3+ selective turn-on fluorescence probe in aqueous methanol. The structure of L has been established from different spectroscopic data and confirmed by X-ray crystallography. Under optimum conditions, the fluorescence intensity of L increases linearly from 1.0 x 10(-6) to 52 x 10(-6) M Cr3+ with a detection limit of 1.5 x 10(-7) M. L also exhibits good cell permeability and can detect intracellular Cr3+ in contaminated living cells.
引用
收藏
页码:2254 / 2258
页数:5
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