A novel polymeric copper(II) compound containing peripheral nitro oxygen bridge and μ-OH core: An unprecedented tetradentate bonding mode of a potentially tridentate Schiff base

被引：20

作者：

Bhaumik, Prasanta Kumar ^{[1
]}

Chattopadhyay, Shouvik ^{[1
]}

机构：

[1] Jadavpur Univ, Inorgan Sect, Dept Chem, Kolkata 700032, India

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 22卷

关键词：

Copper(II); Polymer; Schiff base; mu-OH; Crystal structure; CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; EPR-SPECTRA; COMPLEXES; LIGANDS; BINUCLEAR; CHEMISTRY; CLUSTER;

D O I：

10.1016/j.inoche.2012.05.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A copper(II) compound ([LCu(mu-OH)CuL(H2O)]ClO4)(n) (1) [where HL = 2-[(2-dimethylamino-ethylimino)-methyl]-4-nitro-phenol, is a well known Schiff base], has been synthesized and characterized by elemental analysis, IR and UV-Vis spectroscopy and single-crystal X-ray diffraction studies. The compound features a copper(II) polymeric coordination network composed of binuclear species [LCu(mu-OH)CuL(H2O)](+) as building blocks. It crystallizes in monoclinic space group P2(1)/c with cell dimensions a = 22.1453(9), b = 7.8314(3), c = 18.5626(8) and beta = 108.509(3). The potentially tridentate Schiff base shows a tetra-dentate bonding mode for the 1st time. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：14 / 17

页数：4

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