Iron-based metal-organic frameworks integrated into 3D printed ceramic architectures

被引：14

作者：

Salazar-Aguilar, Alma D. ^{[1
,2
,3
]}

Quintanilla, Asuncion ^{[2
]}

Vega-Diaz, Sofia M. ^{[1
]}

Casas, Jose A. ^{[2
]}

Miranzo, Pilar ^{[3
]}

Osendi, M. Isabel ^{[3
]}

Belmonte, Manuel ^{[3
]}

机构：

[1] Tecnol Nacl Mexico, Inst Tecnol Celaya, Dept Ingn Quim, Av Garcia Cubas Pte 600 Esq Ave Tecnol, Celaya 38010, Guanajuato, Mexico

[2] Univ Autonoma Madrid, Chem Engn Dept, Ctra Colmenar Km 15, Madrid 28049, Spain

[3] Inst Ceram & Glass ICV CSIC, Campus Cantoblanco,Kelsen 5, Madrid 28049, Spain

来源：

OPEN CERAMICS | 2021年 / 5卷

关键词：

3D printing; MOF; Ceramics; Catalysis; Selective oxidation; Phenol;

D O I：

10.1016/j.oceram.2020.100047

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The promising applications of metal-organic frameworks (MOF) can be widened if these materials were additive manufactured to develop three-dimensional (3D) MOF architectures. In this work, iron-based MOF/silicon carbide (SiC) composite aqueous inks with a high solids content (64 wt%) are printed into 3D periodic lattices by a direct ink writing technique (Robocasting). MOF appear fully integrated within the cellular architectures, which display total porosities in the range of 74-78% depending on the scaffold design. The 3D MOF-Fe/SiC structures exhibit good mechanical strength (similar to 4.6 MPa) and a semiconductor-like behaviour. The structures show a remarkable response in the hydroxylation of phenol with hydrogen peroxide, demonstrating high selectivity and yield to dihydroxybenzene species.

引用

页数：6

共 18 条

[1]

Centi G., 2012, Selective oxidation by heterogeneous catalysis

[2] Direct ink writing of hierarchical porous alumina-stabilized emulsions: Rheology and printability [J].

Chan, Shareen S. L. ;

Sesso, Mitchell L. ;

Franks, George V. .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2020, 103 (10) :5554-5566

[3] Formulation of Metal-Organic Framework Inks for the 3D Printing of Robust Microporous Solids toward High-Pressure Gas Storage and Separation [J].

Dhainaut, Jeremy ;

Bonneau, Mickaele ;

Ueoka, Ryota ;

Kanamori, Kazuyoshi ;

Furukawa, Shuhei .

ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (09) :10983-10992

[4] Colorimetric determination of hydrogen peroxide [J].

Eisenberg, GM .

INDUSTRIAL AND ENGINEERING CHEMISTRY-ANALYTICAL EDITION, 1943, 15 :327-328

[5] Combining additive manufacturing and catalysis: a review [J].

Hurt, C. ;

Brandt, M. ;

Priya, S. S. ;

Bhatelia, T. ;

Patel, J. ;

Selvakannan, P. R. ;

Bhargava, S. .

CATALYSIS SCIENCE & TECHNOLOGY, 2017, 7 (16) :3421-3439

[6] Metal-organic frameworks: Structures and functional applications [J].

Jiao, Long ;

Seow, Joanne Yen Ru ;

Skinner, William Scott ;

Wang, Zhiyong U. ;

Jiang, Hai-Long .

MATERIALS TODAY, 2019, 27 :43-68

[7] 3D-Printing of Pure Metal-Organic Framework Monoliths [J].

Lim, Gwendolyn J. H. ;

Wu, Yue ;

Shah, Bhuvan B. ;

Koh, J. Justin ;

Liu, Connie K. ;

Zhao, Dan ;

Cheetham, Anthony K. ;

Wang, John ;

Ding, Jun .

ACS MATERIALS LETTERS, 2019, 1 (01) :147-153

[8] 3D printing of metal -organic frameworks decorated hierarchical porous ceramics for high -e fficiency catalytic degradation [J].

Liu, Desheng ;

Jiang, Pan ;

Li, Xiaochun ;

Liu, Jianxi ;

Zhou, Lincheng ;

Wang, Xiaolong ;

Zhou, Feng .

CHEMICAL ENGINEERING JOURNAL, 2020, 397

[9] 3D-Printed MOF-Derived Hierarchically Porous Frameworks for Practical High-Energy Density Li-O2 Batteries [J].

Lyu, Zhiyang ;

Lim, Gwendolyn J. H. ;

Guo, Rui ;

Kou, Zongkui ;

Wang, Tingting ;

Guan, Cao ;

Ding, Jun ;

Chen, Wei ;

Wang, John .

ADVANCED FUNCTIONAL MATERIALS, 2019, 29 (01)

[10] Microstructural designs of spark-plasma sintered silicon carbide ceramic scaffolds [J].

Roman-Manso, B. ;

De Pablos, A. ;

Belmonte, M. ;

Osendi, M. I. ;

Miranzo, P. .

BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO, 2014, 53 (02) :93-100

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