Self-Oscillating Polymer Brushes

被引：57

作者：

Masuda, Tsukuru ^{[1
]}

Hidaka, Mio ^{[1
]}

Murase, Yoko ^{[1
]}

Akimoto, Aya Mizutani ^{[1
]}

Nagase, Kenichi ^{[2
]}

Okano, Teruo ^{[2
]}

Yoshida, Ryo ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Mat Engn, Bunkyo Ku, Tokyo 1138656, Japan

[2] Tokyo Womens Med Univ, Inst Adv Biomed Engn & Sci, Tokyo, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 29期

关键词：

ATRP; functional surfaces; oscillating reactions; polymer brushes; ruthenium; TRANSFER RADICAL POLYMERIZATION; BELOUSOV-ZHABOTINSKY REACTION; SURFACE; TRANSPORT; DRIVEN;

D O I：

10.1002/anie.201301988

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An autonomous functional surface has been designed by using self-oscillating polymers that convert the chemical energy of the Belousov-Zhabotinsky reaction into conformational changes of the polymer chains (see picture: red: hydrophobic/collapsed, green: hydrophilic/extended). Self-oscillating polymer brushes were grafted onto the inner surface of a glass capillary, and autonomous propagation of a chemical wave was observed. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7468 / 7471

页数：4

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