A new strategy to produce low-density polyethylene (LDPE)-based composites simultaneously with high flame retardancy and high mechanical properties

被引:25
作者
Shen, Liguo [1 ]
Li, Jianxi [3 ]
Li, Renjie [1 ]
Lin, Hongjun [1 ,2 ]
Chen, Jianrong [1 ]
Liao, Bao-Qiang [2 ]
机构
[1] Zhejiang Normal Univ, Coll Geog & Environm Sci, Jinhua 321004, Peoples R China
[2] Lakehead Univ, Dept Chem Engn, 955 Oliver Rd, Thunder Bay, ON P7B 5E1, Canada
[3] CGN DELTA Jiangsu Plast & Chem Co Ltd, Suzhou 215400, Peoples R China
基金
中国国家自然科学基金;
关键词
Composites; Thermal properties; Low-density polyethylene; Flame retardance; Blending; MULTIWALLED CARBON NANOTUBES; MAGNESIUM-HYDROXIDE; SURFACE MODIFICATION; CROSS-LINKING; RADIATION; MEMBRANE; LDPE; ATH; NANOCOMPOSITES; PERFORMANCE;
D O I
10.1016/j.apsusc.2017.12.149
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, a new strategy which blends low-density polyethylene (LDPE), magnesium hydroxide (MH) and lauryl acrylate by electron-beam radiation for production of LDPE-based composites with high performance was proposed. It was found that, MH played main roles in flame retardancy but reduced processing flow and mechanical properties of the composites. Meanwhile, melt flow rate (MFR) increased while viscosity of the composites decreased with lauryl acrylate content increased, facilitating LDPE composites processing. Electron beam radiation could prompt crosslinking of lauryl acrylate, which significantly enhanced the mechanical properties of LDPE composites. Meanwhile, lauryl acrylate addition only slightly decreased the flame retardancy, suggesting that LDPE composites could remain high flame retardancy even when lauryl acrylate content was high. The study highly demonstrated the feasibility to produce LDPE-based composites simultaneously with high flame retardancy and high mechanical properties by the blending strategy provided in this study. (c) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:75 / 81
页数:7
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