NMR spectra of metallated alkanolammonium ionic liquids

被引：10
|
作者：
Ushakov, I. A. [1 ]
Voronov, V. K. [1 ]
Grishmanovskii, D. S. [1 ]
Adamovich, S. N. [2 ]
Mirskov, R. G. [2 ]
Mirskova, A. N. [2 ]
机构：
[1] Irkutsk State Tech Univ, Irkutsk 664074, Russia
[2] Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2015年 / 64卷 / 01期
关键词：
triethanolamine; metallated (2-hydroxyethyl)ammonium ionic liquids; NMR spectroscopy;
D O I：
10.1007/s11172-015-0821-x
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
According to the (1)De, D-13, and N-15 NMR spectral data, metallated alkanolammonium ionic liquids exist as equilibrium of mono-, bi-, and tricyclic structures under the biomimetic conditions (De(2)D, 25 A degrees C). The equilibrium shift depends on the metal nature and affects the change of all parameters in the NMR spectra.
引用
收藏
页码：58 / 61
页数：4
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