Supramolecular tuning of energy transfer efficiency and direction in a bis(styryl) dye-crown ether conjugate

被引：6

作者：

Berdnikova, Daria V. ^{[1
,2
]}

Fedorov, Yuri V. ^{[1
]}

Fedorova, Olga A. ^{[1
]}

Jonusauskas, Gediminas ^{[3
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilova Str 28, Moscow 119991, Russia

[2] RUDN Univ, Mikluho Maklaya Str 6, Moscow 117198, Russia

[3] Bordeaux Univ, Lab Ondes & Mat Aquitaine, UMR CNRS 5798, F-33405 Talence, France

来源：

DYES AND PIGMENTS | 2018年 / 151卷

基金：

俄罗斯科学基金会;

关键词：

Bis(styryl) dye; Energy transfer; FRET; Crown ether; Cation complexation; Protonation; OPTICAL-PROPERTIES; COMPLEXES; BENZO-15-CROWN-5; CONSTRUCTION; RESONANCE; RADICALS; CATIONS;

D O I：

10.1016/j.dyepig.2017.12.068

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The control of the energy transfer (FRET) in a novel bischromophoric styryl(pyridinium) dye bearing two different crown ether residues is presented. Complexation of the dye with metal cations allows to tune the FRET efficiency without changing the transfer direction or to switch the FRET off, whereas protonation launches the FRET process in the opposite direction relative to the molecular structure.

引用

页码：227 / 232

页数：6

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