Heteroleptic tris-cyclometalated iridium(III) complexes supported by an o-carboranyl-pyridine ligand

被引：39

作者：

Bae, Hye Jin ^{[1
]}

Kim, Hyungjun ^{[1
]}

Lee, Kang Mun ^{[1
]}

Kim, Taewon ^{[2
,3
]}

Eo, Maengsun ^{[1
]}

Lee, Yoon Sup ^{[1
]}

Do, Youngkyu ^{[1
]}

Lee, Min Hyung ^{[2
,3
]}

机构：

[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea

[2] Univ Ulsan, Dept Chem, Ulsan 680749, South Korea

[3] Univ Ulsan, EHSRC, Ulsan 680749, South Korea

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 24期

基金：

新加坡国家研究基金会;

关键词：

POLYHEDRAL BORANES; RHODIUM COMPLEXES; HIGHLY EFFICIENT; DERIVATIVES; PHOSPHORESCENCE; EMISSION; POLYMERIZATION; SUBSTITUTION; AROMATICITY; REACTIVITY;

D O I：

10.1039/c3dt51019k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Heteroleptic tris-cyclometalated Ir(III) complexes supported by the o-carboranyl-pyridine (CBpy) as a novel (CN)-N-boolean AND chelating ligand were synthesized and characterized. While the CBpy ligand contributes to the electronic stabilization of complexes, their photophysical properties are dominated by 2-arylpyridine ligands.

引用

页码：8549 / 8552

页数：4

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