Large-scale synthesis of Li1.2V3O8 as a cathode material for lithium secondary battery via a soft chemistry route

被引:21
作者
Cao, Xiaoyu [2 ]
Xie, Lingling [2 ]
Zhan, Hui [1 ]
Zhou, Yunhong [1 ]
机构
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
[2] Henan Univ Technol, Sch Chem & Chem Engn, Zhengzhou 450001, Peoples R China
关键词
Sol-gel chemistry; X-ray diffraction; Electron microscopy; Electrochemical measurements; Electrochemical properties; LIV3O8; BEHAVIOR;
D O I
10.1016/j.materresbull.2008.06.008
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Layered Li1.2V3O8 has been efficiently prepared via a sol-gel method. XRD and particle size analysis indicate that the final product with monoclinic structure consists of homogeneously distributed particles whose sizes are in a very narrow range. There are two different water molecules in the compound according to TGA and DTA. The structural water works as a pillar in the structure and is lost at higher temperature than the combined water. The as-prepared material was also compared with the one synthesized from the conventional solid-state method in terms of their morphology, electrochemistry capacity and electrodynamic characteristics. As a result, the Li1.2V3O8 obtained at 300 degrees C for 10 h has excellent electrochemical properties. A high-first discharge capacity of 286.4 mAh/g was observed at a current rate of C/5 between 1.7 and 3.8 V and the structure of Li1.2V3O8 remains stable in the subsequent cycles. EIS calculation suggests a better diffusion path for lithium ions in as-prepared material than in the solid-state compound. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:472 / 477
页数:6
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