Unexpected trends in halogen-bond based noncovalent adducts

被引：131

作者：

Huber, Stefan M. ^{[1
]}

Jimenez-Izal, Elisa ^{[2
,3
]}

Ugalde, Jesus M. ^{[2
,3
]}

Infante, Ivan ^{[2
,3
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany

[2] Univ Basque Country, Kimika Fak, Donostia San Sebastian 20080, Euskadi, Spain

[3] Donostia Int Phys Ctr, Donostia San Sebastian 20080, Euskadi, Spain

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 62期

关键词：

COMPLEXES; THERMODYNAMICS; CHLORIDE; ION; BR;

D O I：

10.1039/c2cc33304j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unexpected trends in the strengths of halogen-bond based adducts of CY3I (Y = F, Cl, Br, I) with two typical Lewis bases (chloride and trimethylamine) show that the halogen-bond donor strength (Lewis acidity) of a compound R-X is not necessarily increased with higher electronegativity of the (carbon-based) group R.

引用

页码：7708 / 7710

页数：3

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