Design, Synthesis, and Electrofluorochromism of New Triphenylamine Derivatives with AIE-Active Pendent Groups

被引：85
作者：
Liu, Hsiang-Ting [1 ]
Huang, Chiao-Ling [1 ]
Liou, Guey-Sheng [1 ,2 ]
机构：
[1] Natl Taiwan Univ, Inst Polymer Sci & Engn, Taipei 10617, Taiwan
[2] Natl Taiwan Univ, Adv Res Ctr Green Mat Sci & Technol, Taipei 10617, Taiwan
来源：
ACS APPLIED MATERIALS & INTERFACES | 2019年 / 11卷 / 12期
关键词：
AIE; electrochromism; triphenylamine; electrofluorochromism; triphenylethylene; benzo[b]thiophene-1; 1-dioxide; AGGREGATION-INDUCED EMISSION; AROMATIC POLYAMIDES; ELECTROCHROMISM; PHOTOLUMINESCENCE; TETRAPHENYLETHENE; LUMINESCENCE; EMITTERS; SYSTEMS; YELLOW; WINDOW;
D O I：
10.1021/acsami.9b00659
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Triphenylamine (TPA) and 4,4'-dimethoxy-triphenylamine (TPAOMe) derivatives were successfully linked with two high-performance AlEgens, triphenylethylene (TPE) and benzo[b]thiophene-1,1-dioxide (BTO), to obtain four aggregation-induced emission and electro-active materials, TPETPA, BTOTPA, TPETPAOMe, and BTOTPAOMe. The effects on photoluminescence characteristics and electrochromic (EC) and electrofluorochromic (EFC) behaviors in cross-linking gel-type devices derived from the prepared materials were systematically investigated. Furthermore, heptyl viologen was introduced into the EFC devices to enhance EC performance including lower working potential, faster switching time, and superior stability.
引用
收藏
页码：11684 / 11690
页数：7
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