Electrical and magnetic properties of DED salts

被引:1
|
作者
Naito, T
Inabe, T
Arai, E
Tamura, M
Nishio, Y
Kajita, K
Kato, R
Kobayashi, A
Kobayashi, H
机构
[1] TOHO UNIV,DEPT CHEM,FUNABASHI,CHIBA 274,JAPAN
[2] UNIV TOKYO,INST SOLID STATE PHYS,MINATO KU,TOKYO 106,JAPAN
[3] UNIV TOKYO,DEPT CHEM,BUNKYO KU,TOKYO 113,JAPAN
[4] INST MOL SCI,OKAZAKI,AICHI 444,JAPAN
关键词
organic conductors based on radical cation salts; transport measurements; magnetic measurements; specific heat;
D O I
10.1016/S0379-6779(97)80917-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The temperature dependence of the electrical resistivity of (DED)(2)PF6(THF)(2), where DED is thiadiazoleethylenedithiodiselenadithiafulvalene, is metallic down to similar to 20 K. At lower temperatures the resistivity rises proportionally to the logarithm of temperature, followed by a saturation of the resistivity upturn at around 1 K. The magnetic susceptibility exhibits Curie-like behavior down to similar to 20 K, and chi T suddenly goes towards zero at lower temperatures. Such behaviour indicates that this salt could be a rare example of 'purely organic' systems whose electrical behavior at low temperatures might be best explained as a result of Kondo effect.
引用
收藏
页码:1815 / 1816
页数:2
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