Syntheses, Crystal Structures, Thermal Stability, and Fluorescence Properties of Zinc(II) Complexes With Tridentate Schiff Bases

被引：8

作者：

Qian, Shao-Song ^{[1
]}

Li, Hai-Hua ^{[2
]}

Zhu, Hui ^{[1
]}

Yang, Zhong-Ming ^{[1
]}

You, Zhong-Lu ^{[2
]}

Zhu, Hai-Liang ^{[1
]}

机构：

[1] Shandong Univ Technol, Sch Life Sci, Zibo 255049, Peoples R China

[2] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 04期

关键词：

fluorescent; crystal structure; Schiff base; thermal stability; zinc(II) complex; ANTIBACTERIAL ACTIVITIES; CADMIUM(II) COMPLEXES; COPPER(II); ZN(II); NICKEL(II); LIGANDS;

D O I：

10.1080/15533174.2012.740742

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new mononuclear Schiff base zinc(II) complexes, [Zn (NMP)(MeCOO)] (1) and [ZnBr2(MP)]center dot MeOH center dot H2O (2) (NMP = 4-nitro-2-[(3-morpholin-4-ylpropylimino)methyl]phenolate; MP = 2-[(3-morpholin-4-ylpropylimino)methyl]phenolate), have been synthesized from the similar tridentate Schiff base ligands. The complexes were characterized by elemental analysis, infrared spectra, and single-crystal X-ray diffraction. The Zn atom in 1 is five-coordinated in a distorted Squire-pyramidal geometry by the NNO donor set of NMP and two O atoms of an acetate ligand. The Zn atom in 2 is four-coordinated in a tetrahedral geometry by the imino N and phenolate O atoms of MP and two Br atoms. The thermal stability and fluorescence properties of the complexes have also been determined.

引用

页码：412 / 416

页数：5

共 50 条

[31] Synthesis and crystal structures of Manganese(IV) complexes with tridentate schiff bases
Peng, D. L.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2013, 39 (08) : 603 - 608
[32] Syntheses and crystal structures of two novel dinuclear copper(II) and zinc(II) complexes derived from flexible Schiff bases
Sun, Yu-Xi
You, Zhong-Lu
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (8-9): : 1566 - 1569
[33] Syntheses, Crystal Structures, and Characterizations of Nickel(II) Complexes with Schiff Bases and Thiocyanate Ligands
Li, Xiao-Hui
Xu, Gui-Mei
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (05) : 355 - 358
[34] Copper(II) complexes with neutral Schiff bases: Syntheses, crystal structures and DNA interactions
Pal, Abhijit
Biswas, Bhaskar
Mondal, Sunil Kanti
Lin, Chia-Her
Ghosh, Rajarshi
POLYHEDRON, 2012, 31 (01) : 671 - 675
[35] Synthesis, crystal structures, and catalytic properties of two oxidovanadium(V) complexes with tridentate Schiff bases
Peng, D. L.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2017, 43 (06) : 404 - 410
[36] Synthesis, crystal structures, and catalytic properties of two oxidovanadium(V) complexes with tridentate Schiff bases
D. L. Peng
Russian Journal of Coordination Chemistry, 2017, 43 : 404 - 410
[37] Syntheses, Characterization, and Crystal Structures of Nickel Complexes Derived From Tridentate Schiff Bases and Thiocyanate Mixed Ligands
Yuan, Chun-Lan
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2014, 44 (04) : 482 - 485
[38] Syntheses, characterization, and crystal structures of two dinuclear nickel(II) and copper(II) complexes with Schiff bases
Hui, R. H.
Zhou, P.
You, Z. L.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2010, 36 (07) : 525 - 529
[39] Syntheses, characterization, and crystal structures of two dinuclear nickel(II) and copper(II) complexes with Schiff bases
R. H. Hui
P. Zhou
Z. L. You
Russian Journal of Coordination Chemistry, 2010, 36 : 525 - 529
[40] Syntheses, Characterization and Crystal Structures of Schiff Base Zinc(II) Complexes with Antibacterial Activity
Peng, Dong-Lai
Sun, Nan
ACTA CHIMICA SLOVENICA, 2018, 65 (04) : 895 - 901

← 1 2 3 4 5 →