Syntheses, Crystal Structures, Thermal Stability, and Fluorescence Properties of Zinc(II) Complexes With Tridentate Schiff Bases

被引：8

作者：

Qian, Shao-Song ^{[1
]}

Li, Hai-Hua ^{[2
]}

Zhu, Hui ^{[1
]}

Yang, Zhong-Ming ^{[1
]}

You, Zhong-Lu ^{[2
]}

Zhu, Hai-Liang ^{[1
]}

机构：

[1] Shandong Univ Technol, Sch Life Sci, Zibo 255049, Peoples R China

[2] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 04期

关键词：

fluorescent; crystal structure; Schiff base; thermal stability; zinc(II) complex; ANTIBACTERIAL ACTIVITIES; CADMIUM(II) COMPLEXES; COPPER(II); ZN(II); NICKEL(II); LIGANDS;

D O I：

10.1080/15533174.2012.740742

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new mononuclear Schiff base zinc(II) complexes, [Zn (NMP)(MeCOO)] (1) and [ZnBr2(MP)]center dot MeOH center dot H2O (2) (NMP = 4-nitro-2-[(3-morpholin-4-ylpropylimino)methyl]phenolate; MP = 2-[(3-morpholin-4-ylpropylimino)methyl]phenolate), have been synthesized from the similar tridentate Schiff base ligands. The complexes were characterized by elemental analysis, infrared spectra, and single-crystal X-ray diffraction. The Zn atom in 1 is five-coordinated in a distorted Squire-pyramidal geometry by the NNO donor set of NMP and two O atoms of an acetate ligand. The Zn atom in 2 is four-coordinated in a tetrahedral geometry by the imino N and phenolate O atoms of MP and two Br atoms. The thermal stability and fluorescence properties of the complexes have also been determined.

引用

页码：412 / 416

页数：5

共 50 条

[21] Synthesis, crystal structures, and magnetic properties of tetranuclear nickel(II) and copper(II) complexes with tridentate Schiff bases
Qian, Shao-Song
Zhao, Yue
Zhen, Miao-Miao
Zhang, Cheng-Lu
You, Zhong-Lu
Zhu, Hai-Liang
TRANSITION METAL CHEMISTRY, 2013, 38 (01) : 63 - 68
[22] Synthesis and Crystal Structures of Polymeric Copper(II) Complexes Derived from Tridentate Schiff Bases
Xue-Song Lin
Ya-Li Sang
Wen-Min Xiao
Journal of Chemical Crystallography, 2012, 42 : 578 - 582
[23] Crystal structures of azido or thiocyanato-coordinated nickel(II) complexes with tridentate Schiff bases
S. -S. Qian
M. Zhang
Zhong-Lu You
Hai-Liang Zhu
Journal of Structural Chemistry, 2013, 54 : 926 - 930
[24] Synthesis and Crystal Structures of Bromido-Coordinated Zinc(II) and Copper(II) Complexes with Schiff Bases
Miao, Jian-Ying
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2011, 41 (06) : 689 - 693
[25] Synthesis, crystal structures, and magnetic properties of tetranuclear nickel(II) and copper(II) complexes with tridentate Schiff bases
Shao-Song Qian
Yue Zhao
Miao-Miao Zhen
Cheng-Lu Zhang
Zhong-Lu You
Hai-Liang Zhu
Transition Metal Chemistry, 2013, 38 : 63 - 68
[26] Zinc(II) and mercury(II) complexes with Schiff bases: syntheses, spectral, and structural characterization
Dubey, R. K.
Baranwal, P.
Jha, A. K.
JOURNAL OF COORDINATION CHEMISTRY, 2012, 65 (15) : 2645 - 2656
[27] Syntheses, Crystal Structures and Properties of Zn(II) and Cd(II) Complexes with Acylhydrazone Schiff Base
Chen Yan-Min
Feng Ying-Jian
Cai Min-Yu
Fang Ya-Qian
Xie Qing-Fan
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2018, 34 (01) : 123 - 128
[28] Syntheses, Characterization, and Crystal Structures of Nickel Complexes Derived From Tridentate Schiff Bases and Thiocyanate Mixed Ligands
Yuan, Chun-Lan
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2014, 44 (04) : 482 - 485
[29] Synthesis and crystal structure of three new copper(II) complexes with a tridentate amine and its Schiff bases
Sain, Saugata
Saha, Rajat
Mostafa, Golam
Fleck, Michel
Bandyopadhyay, Debasis
POLYHEDRON, 2012, 31 (01) : 82 - 88
[30] Syntheses and crystal structures of two tetranuclear copper(II) complexes with Schiff bases
Zhang, Na
You, Zhong-Lu
TRANSITION METAL CHEMISTRY, 2010, 35 (04) : 437 - 440

← 1 2 3 4 5 →