Syntheses, Crystal Structures, Thermal Stability, and Fluorescence Properties of Zinc(II) Complexes With Tridentate Schiff Bases

被引：8
|
作者：
Qian, Shao-Song [1 ]
Li, Hai-Hua [2 ]
Zhu, Hui [1 ]
Yang, Zhong-Ming [1 ]
You, Zhong-Lu [2 ]
Zhu, Hai-Liang [1 ]
机构：
[1] Shandong Univ Technol, Sch Life Sci, Zibo 255049, Peoples R China
[2] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 04期
关键词：
fluorescent; crystal structure; Schiff base; thermal stability; zinc(II) complex; ANTIBACTERIAL ACTIVITIES; CADMIUM(II) COMPLEXES; COPPER(II); ZN(II); NICKEL(II); LIGANDS;
D O I：
10.1080/15533174.2012.740742
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new mononuclear Schiff base zinc(II) complexes, [Zn (NMP)(MeCOO)] (1) and [ZnBr2(MP)]center dot MeOH center dot H2O (2) (NMP = 4-nitro-2-[(3-morpholin-4-ylpropylimino)methyl]phenolate; MP = 2-[(3-morpholin-4-ylpropylimino)methyl]phenolate), have been synthesized from the similar tridentate Schiff base ligands. The complexes were characterized by elemental analysis, infrared spectra, and single-crystal X-ray diffraction. The Zn atom in 1 is five-coordinated in a distorted Squire-pyramidal geometry by the NNO donor set of NMP and two O atoms of an acetate ligand. The Zn atom in 2 is four-coordinated in a tetrahedral geometry by the imino N and phenolate O atoms of MP and two Br atoms. The thermal stability and fluorescence properties of the complexes have also been determined.
引用
收藏
页码：412 / 416
页数：5
相关论文
共 50 条
  • [1] Synthesis, crystal structures, and fluorescent properties of zinc and cadmium(II) complexes with tridentate Schiff bases
    Qian, Shao-Song
    Zhang, Mei
    Wang, Yi-Nuo
    Tian, Feng-Yu
    Liu, Lei
    You, Zhong-Lu
    Zhu, Hai-Liang
    JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (06) : 1006 - 1015
  • [2] Syntheses, crystal structures, and fluorescence properties of Zinc(II) complexes with multi-dentate Schiff bases
    Qian, S. S.
    Cheng, X. S.
    Ren, J. Q.
    You, Z. L.
    Zhu, H. L.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2013, 39 (12) : 836 - 843
  • [3] Syntheses, characterization, crystal structures and fluorescence property of Zinc(II) complexes with Schiff bases
    Qin, J.
    Sun, Y.
    Xia, Z. N.
    Zhang, Y.
    Zhao, X. L.
    You, Z. L.
    Zhu, H. L.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2016, 42 (05) : 330 - 337
  • [4] Syntheses, Characterization, and Crystal Structures of Bromido-Coordinated Zinc(II) Complexes With Multidentate Schiff Bases
    Sheng, Gui-Hua
    Cheng, Xiao-Shan
    Ren, Jin-Qi
    You, Zhong-Lu
    Zhu, Hai-Liang
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (04) : 567 - 571
  • [5] Syntheses, characterization, crystal structures and fluorescence property of Zinc(II) complexes with Schiff bases
    J. Qin
    Y. Sun
    Z. N. Xia
    Y. Zhang
    X. L. Zhao
    Z. L. You
    H. L. Zhu
    Russian Journal of Coordination Chemistry, 2016, 42 : 330 - 337
  • [6] Syntheses, Crystal Structures and Properties of Bis-Schiff Bases Containing Carboxyl and Their Copper(II) Complexes
    Liang Chu-Xin
    Liu Zheng
    Liang Qiu-Qun
    Tang Qun
    Li Hai-Ying
    Huang He-Xiang
    Zhang Shu-Fen
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2019, 35 (07) : 1130 - 1138
  • [7] Synthesis, crystal structure and fluorescence properties of two dinuclear zinc(II) complexes incorporating tridentate (NNO) Schiff bases
    Shit, Shyamapada
    Nandy, Madhusudan
    Saha, Dipankar
    Zhang, Lei
    Schmitt, Wolfgang
    Rizzoli, Corrado
    Row, Tayur N. Guru
    JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (16) : 2403 - 2414
  • [8] Syntheses, structures and properties of cadmium(II) halide complexes containing tridentate Schiff bases
    Kundu, Subhasish
    Roy, Subhasis
    Bhar, Kishalay
    Sutradhar, Dipu
    Mitra, Partha
    Ghosh, Barindra Kumar
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2013, 52 (11): : 1404 - 1410
  • [9] Syntheses, characterizations and crystal structures of nickel(II) and copper(II) complexes with a tridentate Schiff base
    Bhowmik, Prasanta
    Bhaumik, Prasanta Kumar
    Chattopadhyay, Shouvik
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2014, 91 (11) : 2019 - 2025
  • [10] Syntheses, Characterization and Crystal Structures of Schiff Base Zinc(II) Complexes with Antibacterial Activity
    Peng, Dong-Lai
    Sun, Nan
    ACTA CHIMICA SLOVENICA, 2018, 65 (04) : 895 - 901
12345