Chromium(0)-Promoted [6π+2π] Cycloadditions of Allenes with Cycloheptatriene

被引：25

作者：

Rigby, James H. ^{[1
]}

Laurent, Stephane B. ^{[1
]}

Kamal, Zeeshan ^{[1
]}

Heeg, Mary Jane ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 24期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1021/ol802401a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photoinitiated [6 pi + 2 pi] cycloadditions of allenes with (eta(6)-cycloheptatriene)tricarbonylchromium(0) (1) are described. An example of asymmetric induction obtained by reaction of 1 with a chiral 1,3-disubstituted allene is also reported.

引用

页码：5609 / 5612

页数：4

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