Molybdenum(VI) complexes containing differing CIS multiply-bonded ligands: Some structural consequences of competing pi-donor groups

被引：31

作者：

Copley, RCB ^{[1
]}

Dyer, PW ^{[1
]}

Gibson, VC ^{[1
]}

Howard, JAK ^{[1
]}

Marshall, EL ^{[1
]}

Wang, WY ^{[1
]}

Whittle, B ^{[1
]}

机构：

[1] UNIV DURHAM,SCI LABS,DEPT CHEM,DURHAM DH1 3LE,ENGLAND

来源：

POLYHEDRON | 1996年 / 15卷 / 18期

关键词：

D O I：

10.1016/0277-5387(96)00008-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mixed bis(imido) molybdenum complex Mo(N-2,6-(Pr2C6H3)-C-i)(N-Bu(t))Cl-2(dme) (1; dme = 1,2-dimethoxyethane) is accessible in multi-gram quantities upon treatment of Na2MoO4 with equimolar quantities of H-2,N-2,6-Pr-2(i),C6H3 and Bu(t)NH(2) in the presence of excess NEt(3) and chlorotrimethylsilane. Treatment of Na2MoO4 with one equivalent of 1-adamantamine under analogous conditions afforded Mo(N-1-adamantyl)(O)Cl-2(dme) (2). The molecular structures of 1 and 2 are reported. A rationale for the orientation of the imido aryl substituent based on electronic considerations is proposed. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：3001 / 3008

页数：8

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