Synthesis of enantiomerically pure sulfenimines and sulfinimines derived from (+)-camphor

被引：4

作者：

Li, Y ^{[1
]}

Zhu, W ^{[1
]}

Cheng, ZY ^{[1
]}

Yang, GS ^{[1
]}

机构：

[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 1999年 / 29卷 / 15期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1080/00397919908086426

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of chiral sulfenimines were synthesized by reaction of thiol derived from (+)-camphor with NCS, liquid NH3 and aldehydes or ketones. Oxidation of the sulfenimines with MCPBA provided enantiomerically pure sulfinimines in excellent yields, compounds which are very useful in the asymmetric synthesis of amine derivatives.

引用

页码：2645 / 2656

页数：12

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