A novel nanometer-scale "gold electrode-molecular wires-silver" junction: An efficient test bed for electrochemical investigation of electron transportation through molecular wires in self-assembled monolayers

被引:4
作者
Li, GR [1 ]
Lin, HW [1 ]
Wang, XH [1 ]
Wang, FS [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Grad Sch, Changchun 130022, Peoples R China
关键词
gold electrode-molecular wires-silver junction; electrochemical; electron transportation; molecular wires; self-assembled monolayers;
D O I
10.1016/j.elecom.2005.10.017
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A novel "gold electrode-molecular wires-silver" junction was facilely fabricated for electrochemical study on the electron transportation through molecular wires. Rapid electron transportation through this sandwich-like structure was indeed observed by cyclic voltammograms and ac impedance measurements. Since rather reproducible and reliable results are easily available by electrochemical techniques, it would be an efficient and reliable test bed for electrochemical investigation of charge transportation through molecular wires in self-assembled monolayers on electrodes. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:33 / 37
页数:5
相关论文
共 17 条
  • [1] Charge hopping in molecular wires as a sequence of electron-transfer reactions
    Berlin, YA
    Hutchison, GR
    Rempala, P
    Ratner, MA
    Michl, J
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (19) : 3970 - 3980
  • [2] Chemical and potential-assisted assembly of thiolacetyl-terminated oligo(phenylene ethynylene)s on gold surfaces
    Cai, LT
    Yao, YX
    Yang, JP
    Price, DW
    Tour, JM
    [J]. CHEMISTRY OF MATERIALS, 2002, 14 (07) : 2905 - 2909
  • [3] Large on-off ratios and negative differential resistance in a molecular electronic device
    Chen, J
    Reed, MA
    Rawlett, AM
    Tour, JM
    [J]. SCIENCE, 1999, 286 (5444) : 1550 - 1552
  • [4] FREE-ENERGY AND TEMPERATURE-DEPENDENCE OF ELECTRON-TRANSFER AT THE METAL-ELECTROLYTE INTERFACE
    CHIDSEY, CED
    [J]. SCIENCE, 1991, 251 (4996) : 919 - 922
  • [5] Changes in the electronic properties of a molecule when it is wired into a circuit
    Cui, XD
    Primak, A
    Zarate, X
    Tomfohr, J
    Sankey, OF
    Moore, AL
    Moore, TA
    Gust, D
    Nagahara, LA
    Lindsay, SM
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (34) : 8609 - 8614
  • [6] Electrons are transported through phenylene-ethynylene oligomer monolayers via localized molecular orbitals
    Fan, FRF
    Lai, RY
    Cornil, J
    Karzazi, Y
    Brédas, JL
    Cai, LT
    Cheng, L
    Yao, YX
    Price, DW
    Dirk, SM
    Tour, JM
    Bard, AJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (08) : 2568 - 2573
  • [7] Electrical breakdown of aliphatic and aromatic self-assembled monolayers used as nanometer-thick organic dielectrics
    Haag, R
    Rampi, MA
    Holmlin, RE
    Whitesides, GM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (34) : 7895 - 7906
  • [8] Resistance of alkanethiol molecular wires
    Kaun, CC
    Guo, H
    [J]. NANO LETTERS, 2003, 3 (11) : 1521 - 1525
  • [9] Metal-containing molecular wires and their electron transportation properties
    Lin, HW
    Wang, XH
    Zhao, XJ
    Li, J
    Wang, FS
    [J]. SYNTHETIC METALS, 2003, 135 (1-3) : 239 - 240
  • [10] Maoz R, 2000, ADV MATER, V12, P424, DOI 10.1002/(SICI)1521-4095(200003)12:6<424::AID-ADMA424>3.0.CO