Probing the Effects of Ligand Isomerism in Chiral Luminescent Lanthanide Supramolecular Self-Assemblies: A Europium "Trinity Sliotar" Study

被引：55
作者：
Kotova, Oxana [1 ]
Kitchen, Jonathan A. [1 ]
Lincheneau, Christophe [1 ]
Peacock, Robert D. [2 ]
Gunnlaugsson, Thorfinnur [1 ]
机构：
[1] Univ Dublin, Trinity Coll Dublin, Sch Chem, Trinity Biomed Sci Inst, Dublin 2, Ireland
[2] Univ Glasgow, Sch Chem, Glasgow G12 8QQ, Lanark, Scotland
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 48期
基金：
爱尔兰科学基金会;
关键词：
chirality; lanthanides; luminescence; molecular probes; supramolecular chemistry; CIRCULARLY-POLARIZED LUMINESCENCE; DIRECTED SYNTHESIS; COORDINATION BUNDLES; COMPLEXES; N,N'-BIS(1-PHENYLETHYL)-2,6-PYRIDINEDICARBOXAMIDE; EMISSION; LIFETIME; WATER;
D O I：
10.1002/chem.201303660
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
"Trinity Sliotar" family: Chiral ligands containing pyridyl and naphthalene moieties were synthesized and characterized. These ligands were successfully used for the synthesis of EuIII bundles where chirality of the ligand is successfully transferred onto the lanthanide centre resulting in circularly polarized red luminescence. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：16181 / 16186
页数：6
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