Sorption of Tc(VII) and Am(III) by carbon materials: effect of oxidation

被引:11
作者
Popova, N. N. [1 ]
Bykov, G. L. [1 ]
Petukhova, G. A. [1 ]
Tananaev, I. G. [1 ]
Ershov, B. G. [1 ]
机构
[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119071, Russia
关键词
Sorption; Carbon materials; Radionuclides; Americium;
D O I
10.1007/s10967-013-2659-8
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this work we studied the effect of oxidation on the sorption properties of carbon materials, produced on the basic of activated carbons FAS and VSK in relation to radionuclides Am(III) and Tc(VII). It has been found that the oxidation increases the distribution coefficients for the extraction of radionuclides of sorption nitric acid raising agents. As to identify the mechanism of the oxidation influence on the sorption properties the physical and chemical properties of the synthesized samples (porous surface structure, IR-spectrums etc.) were studied. The possibility of removal of radionuclides from the real industrial solutions of complex composition using of the obtained carbon nanomaterials was investigated.
引用
收藏
页码:1463 / 1468
页数:6
相关论文
共 11 条
[1]  
[Anonymous], 2002, NEW HDB CHEM PROCE 1, P616
[2]   Adsorption of cesium, thallium, strontium and cobalt radionuclides using activated carbon [J].
Hanafi, A. .
JOURNAL OF ATOMIC AND MOLECULAR SCIENCES, 2010, 1 (04) :292-300
[3]  
Myasoedova V.G., 2006, RUSS CHEM J, V50, P55
[4]  
Nakanisi K, 1965, INFRARED SPECTRUMS S
[5]   A study of physicochemical properties of modified carbon nanomaterials intended for sorption extraction of radionuclides I. The influence of the porosity of carbon nanomaterials on their sorption properties with respect to Tc(VII) [J].
Popova, N. N. ;
Bykov, L. G. ;
Petuhova, G. A. ;
Tananaev, I. G. ;
Ershov, B. G. .
PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2012, 48 (06) :665-670
[6]  
Popova NN, 2011, CHIMICHESKAYA TECHNO, V4, P237
[7]  
Popova NN, 2011, 11 INT C MOD SORPT P, P136
[8]  
Tarkovskaya I. A., 1981, OXIDIZED COAL
[9]   Preparation of Spherical Activated Carbon from Furfural, Its Properties and Prospective Applications in Medicine and the National Economy [J].
Tsivadze, A. Yu. ;
Gur'yanov, V. V. ;
Petukhova, G. A. .
PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2011, 47 (05) :612-620
[10]  
Yerankin SV, 2007, INT EUR S WOOD PROC