A new lithium secondary battery system: the sulfur/lithium-ion battery

被引:48
作者
Duan, Bochao [1 ,2 ]
Wang, Weikun [1 ]
Wang, Anbang [1 ]
Yu, Zhongbao [1 ]
Zhao, Hailei [2 ]
Yang, Yusheng [1 ,2 ]
机构
[1] Res Inst Chem Def, Beijing 100191, Peoples R China
[2] Univ Sci & Technol, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
关键词
ADVANCED ANODE MATERIAL; SULFUR COMPOSITE; CATHODE MATERIAL; GRAPHENE OXIDE; ELECTRODE; ELECTROCHEMISTRY; STORAGE; METAL;
D O I
10.1039/c3ta13782a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new lithium secondary battery system, the sulfur/lithium-ion battery, has been constructed by employing a lithium/Sn-C composite anode, a carbyne polysulfide cathode, and a carbonic ester electrolyte. Compared with a lithium/sulfur battery, the use of a lithium/Sn-C composite anode ensures the high safety of the new battery. Meanwhile, the novel battery possesses high-energy characteristics. It delivers a reversible capacity of 500 mA h g(-1) after 50 cycles at a current density of 200 mA g(-1), which ensures a stable specific energy of 410 W h kg(-1). As all of the materials required for the new battery are readily available and low-cost, and the techniques are simple, this new battery has a strong potential for use in industry. Furthermore, there is considerable room for improvement of the energy density of the sulfur/lithium-ion battery, and the new battery is one of the most promising candidates for the next generation of high-performance rechargeable batteries.
引用
收藏
页码:308 / 314
页数:7
相关论文
共 39 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions [J].
Aurbach, D ;
Zinigrad, E ;
Cohen, Y ;
Teller, H .
SOLID STATE IONICS, 2002, 148 (3-4) :405-416
[3]   The application of atomic force microscopy for the study of Li deposition processes [J].
Aurbach, D ;
Cohen, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (11) :3525-3532
[4]   High-performance lithium battery anodes using silicon nanowires [J].
Chan, Candace K. ;
Peng, Hailin ;
Liu, Gao ;
McIlwrath, Kevin ;
Zhang, Xiao Feng ;
Huggins, Robert A. ;
Cui, Yi .
NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35
[5]   Carbon-Silicon Core-Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries [J].
Cui, Li-Feng ;
Yang, Yuan ;
Hsu, Ching-Mei ;
Cui, Yi .
NANO LETTERS, 2009, 9 (09) :3370-3374
[6]   LixNi0.25Mn0.75Oy (0.5 ≤ x ≤ 2, 2 ≤ y ≤ 2.75) compounds for high-energy lithium-ion batteries [J].
Deng, Haixia ;
Belharouak, Ilias ;
Sun, Yang-Kook ;
Amine, Khalil .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (26) :4510-4516
[7]   Nanostructured Sn-C composite as an advanced anode material in high-performance lithium-ion batteries [J].
Derrien, Gaelle ;
Hassoun, Jusef ;
Panero, Stefania ;
Scrosati, Bruno .
ADVANCED MATERIALS, 2007, 19 (17) :2336-+
[8]   Carbyne polysulfide as a novel cathode material for lithium/sulfur batteries [J].
Duan, Bochao ;
Wang, Weikun ;
Wang, Anbang ;
Yuan, Keguo ;
Yu, Zhongbao ;
Zhao, Hailei ;
Qiu, Jingyi ;
Yang, Yusheng .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (42) :13261-13267
[9]   Nano-Sn/Mesoporous Carbon Parasitic Composite as Advanced Anode Material for Lithium-Ion Battery [J].
Duan, Bochao ;
Wang, Weikun ;
Zhao, Hailei ;
Xu, Bin ;
Yuan, Keguo ;
Yang, Yusheng .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (12) :A2092-A2095
[10]   Rechargeable lithiated silicon-sulfur (SLS) battery prototypes [J].
Elazari, Ran ;
Salitra, Gregory ;
Gershinsky, Gregory ;
Garsuch, Arnd ;
Panchenko, Alexander ;
Aurbach, Doron .
ELECTROCHEMISTRY COMMUNICATIONS, 2012, 14 (01) :21-24