A Novel Organocatalytic Asymmetric Transfer Hydrogenation of α,β-Unsaturated Aldehydes

被引：3

作者：

Zhang, Bao-Hua ^{[1
]}

Shi, Lan-Xiang ^{[1
]}

Guo, Rui-Xia ^{[1
]}

机构：

[1] Shijiazhuang Univ, Coll Chem Engn, Shijiazhuang 050035, Peoples R China

来源：

HELVETICA CHIMICA ACTA | 2013年 / 96卷 / 11期

关键词：

Ammonium salt; chiral; Asymmetric hydrogenation; Aldehydes; -unsaturated; Diimides; Diazenes; Hydrogenation;

D O I：

10.1002/hlca.201300029

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

,-Unsaturated aldehydes reacted with diimide (diazene) in the presence of optically active ammonium salt 1 as a catalyst to give the corresponding saturated aldehydes in excellent yields and up to 98:2 er. Attractive features of the asymmetric transfer hydrogenation are its high yields, and chemo-, and enantioselectivities.

引用

页码：2152 / 2154

页数：3

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