Catalytic conversion of fructose and sucrose to 5-hydroxymethylfurfural using simple ionic liquid/DMF binary reaction media

被引：18

作者：

Shi, Jincai ^{[1
]}

Yang, Yan ^{[1
]}

Wang, Ningning ^{[1
]}

Song, Zhanxin ^{[1
]}

Gao, Haiyan ^{[1
]}

Xia, Yongmei ^{[1
,2
]}

Li, Wei ^{[1
]}

Wang, Haijun ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China

[2] Jiangnan Univ, State Key Lab Food Sci & Technol, Wuxi 214122, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2013年 / 42卷

关键词：

5-Hydroxymethylfurfural; Fructose; Ionic liquid; N; N-Dimethylformamide; System; ROOM-TEMPERATURE; SELECTIVE DEHYDRATION; LEVULINIC ACID; EFFICIENT; CELLULOSE; GLUCOSE; DMSO;

D O I：

10.1016/j.catcom.2013.08.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The production of 5-hydroxymethylfurfural (HMF) from carbohydrates has been reported intensively in recent years. HMF is believed to be a versatile platform chemical and the focus of synthesizing it has especially been on the development of efficient catalysts, such as Lewis and Bronsted Acids. On the contrary, herein, we report a novel catalytic system that consists of 1-allyl-3-methylimidazolium chloride ([AMIM]Cl) and N,N-Dimethylformamide (DMF) without any additional metal salts or acids, which leads to reasonable HMF yields (84.9%) and selectivities. In addition, the degradation mechanism of fructose catalyzed by [AMIM]Cl is also proposed in this communication. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：89 / 92

页数：4

共 24 条

[1] Conversion of Fructose into 5-(Hydroxymethyl)furfural in Sulfolane
Caes, Benjamin R.
Raines, Ronald T.
[J]. CHEMSUSCHEM, 2011, 4 (03) : 353 - 356
[2] Insights into the Interplay of Lewis and Bronsted Acid Catalysts in Glucose and Fructose Conversion to 5-(Hydroxymethyl)furfural and Levulinic Acid in Aqueous Media
Choudhary, Vinit
Mushrif, Samir H.
Ho, Christopher
Anderko, Andrzej
Nikolakis, Vladimiros
Marinkovic, Nebojsa S.
Frenkel, Anatoly I.
Sandler, Stanley I.
Vlachos, Dionisios G.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (10) : 3997 - 4006
[3] A Study of the Acid-Catalyzed Hydrolysis of Cellulose Dissolved in Ionic Liquids and the Factors Influencing the Dehydration of Glucose and the Formation of Humins
Dee, Sean J.
Bell, Alexis T.
[J]. CHEMSUSCHEM, 2011, 4 (08) : 1166 - 1173
[4] Efficient selective dehydration of fructose and sucrose into 5-hydroxymethylfurfural (HMF) using dicationic room temperature ionic liquids as a catalyst
Jadhav, Arvind H.
Kim, Hern
Hwang, In Taek
[J]. CATALYSIS COMMUNICATIONS, 2012, 21 : 96 - 103
[5] The First Molecular Level Monitoring of Carbohydrate Conversion to 5-Hydroxymethylfurfural in Ionic Liquids. B2O3uAn Efficient Dual-Function Metal-Free Promoter for Environmentally Benign Applications
Khokhlova, Elena A.
Kachala, Vadim V.
Ananikov, Valentine P.
[J]. CHEMSUSCHEM, 2012, 5 (04) : 783 - 789
[6] Relation between surface acidity and reactivity in fructose conversion into 5-HMF using tungstated zirconia catalysts
Kourieh, R.
Rakic, V.
Bennici, S.
Auroux, A.
[J]. CATALYSIS COMMUNICATIONS, 2013, 30 : 5 - 13
[7] DEHYDRATION OF D-FRUCTOSE (FORMATION OF 5-HYDROXYMETHYL-2-FURALDEHYDE AND LEVULINIC ACID) .3. INFLUENCE OF WATER CONCENTRATION ON DEHYDRATION OF D-FRUCTOSE
KUSTER, BFM
[J]. CARBOHYDRATE RESEARCH, 1977, 54 (02) : 177 - 183
[8] Dehydration of fructose into 5-hydroxymethylfurfural in the presence of ionic liquids
Lansalot-Matras, C
Moreau, C
[J]. CATALYSIS COMMUNICATIONS, 2003, 4 (10) : 517 - 520
[9] Conversion and kinetics study of fructose-to-5-hydroxymethylfurfural (HMF) using sulfonic and ionic liquid groups bi-functionalized mesoporous silica nanoparticles as recyclable solid catalysts in DMSO systems
Lee, Yin-Ying
Wu, Kevin C. -W.
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (40) : 13914 - 13917
[10] Direct, high-yield conversion of cellulose into biofuel
Mascal, Mark
Nikitin, Edward B.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (41) : 7924 - 7926

← 1 2 3 →