An efficient ligand-free method for the transfer hydrogenation of ketones and aldehydes catalyzed by different complexes

被引：7

作者：

Yasar, Sedat ^{[1
]}

Cekirdek, Suzan ^{[1
]}

Akkus Tas, Nilay ^{[1
]}

Yildirim, Semiha ^{[2
]}

Ozdemir, Ismail ^{[3
]}

机构：

[1] Gaziosmanpasa Univ, Fac Sci & Arts, Dept Chem, Tokat, Turkey

[2] Karabuk Univ, Fac Sci, Dept Chem, Karabuk, Turkey

[3] Inonu Univ, Fac Sci & Arts, Dept Chem, Malatya, Turkey

来源：

TURKISH JOURNAL OF CHEMISTRY | 2013年 / 37卷 / 02期

关键词：

Transfer hydrogenation; ruthenium; iridium; palladium; ketone; aldehyde; ASYMMETRIC TRANSFER HYDROGENATION; N-HETEROCYCLIC CARBENES; RUTHENIUM COMPLEXES; IRIDIUM COMPLEXES; ALCOHOLS; RHODIUM;

D O I：

10.3906/kim-1211-29

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A very efficient ligand-free method was developed for the transfer hydrogenation of ketones and aldehydes catalyzed by different metal complexes. With this catalytic system, the catalytic performance and catalytic stability of different Ir, Ru, and Pd complexes were more favorable than those of the previously reported systems for transfer hydrogenation. This ligand-free catalytic system showed good stability and excellent activity even with lower catalyst concentrations for the ketones and aldehydes tested.

引用

页码：292 / 298

页数：7

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